Same spectral signature in liquid-state and solid-state 1H photo-CIDNP NMR spectra of cyclohexanone

Mikhail Panov; Pavlo Bielytskyi; Daniel Gräsing; Alexandra Yurkovskaya; Jörg Matysik

doi:10.1080/00268976.2018.1512722

Same spectral signature in liquid-state and solid-state ¹H photo-CIDNP NMR spectra of cyclohexanone

Mikhail Panov, Pavlo Bielytskyi, Daniel Gräsing, Alexandra Yurkovskaya, Jörg Matysik

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

For the first time, a ¹H solid-state photo-CIDNP effect is reported. The effect is observed in frozen solution of cyclohexanone in 1,4-dioxane-d₈ under magic-angle spinning and continuous irradiation by the full spectrum of a xenon arc lamp. The spectral features show close similarity with those observed by ¹H liquid-state photo-CIDNP NMR.

Язык оригинала	английский
Страницы (с-по)	2756-2761
Число страниц	6
Журнал	Molecular Physics
Том	117
Номер выпуска	19
DOI	https://doi.org/10.1080/00268976.2018.1512722
Состояние	Опубликовано - 2 окт 2019

Доступ к документу

10.1080/00268976.2018.1512722

Link to publication in Scopus

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Цитировать

Panov, M., Bielytskyi, P., Gräsing, D., Yurkovskaya, A., & Matysik, J. (2019). Same spectral signature in liquid-state and solid-state ¹H photo-CIDNP NMR spectra of cyclohexanone. Molecular Physics, 117(19), 2756-2761. https://doi.org/10.1080/00268976.2018.1512722

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title = "Same spectral signature in liquid-state and solid-state 1H photo-CIDNP NMR spectra of cyclohexanone",

abstract = "For the first time, a 1H solid-state photo-CIDNP effect is reported. The effect is observed in frozen solution of cyclohexanone in 1,4-dioxane-d8 under magic-angle spinning and continuous irradiation by the full spectrum of a xenon arc lamp. The spectral features show close similarity with those observed by 1H liquid-state photo-CIDNP NMR.",

keywords = "aliphatic ketones, Biradicals, exchange interaction, hyperpolarisation, magic-angle spinning, MAS, norrish type I photo-reaction, PHOTOSYNTHETIC REACTION CENTERS, BACTERIA, MECHANISM, ELECTRON-DONOR, MAGNETIC-FIELD DEPENDENCE, PHASE, DYNAMIC NUCLEAR-POLARIZATION, BIRADICALS, MAS NMR",

author = "Mikhail Panov and Pavlo Bielytskyi and Daniel Gr{\"a}sing and Alexandra Yurkovskaya and J{\"o}rg Matysik",

year = "2019",

month = oct,

day = "2",

doi = "10.1080/00268976.2018.1512722",

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journal = "Molecular Physics",

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Same spectral signature in liquid-state and solid-state ¹H photo-CIDNP NMR spectra of cyclohexanone. / Panov, Mikhail; Bielytskyi, Pavlo; Gräsing, Daniel; Yurkovskaya, Alexandra; Matysik, Jörg.

В: Molecular Physics, Том 117, № 19, 02.10.2019, стр. 2756-2761.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Same spectral signature in liquid-state and solid-state 1H photo-CIDNP NMR spectra of cyclohexanone

AU - Panov, Mikhail

AU - Bielytskyi, Pavlo

AU - Gräsing, Daniel

AU - Yurkovskaya, Alexandra

AU - Matysik, Jörg

PY - 2019/10/2

Y1 - 2019/10/2

N2 - For the first time, a 1H solid-state photo-CIDNP effect is reported. The effect is observed in frozen solution of cyclohexanone in 1,4-dioxane-d8 under magic-angle spinning and continuous irradiation by the full spectrum of a xenon arc lamp. The spectral features show close similarity with those observed by 1H liquid-state photo-CIDNP NMR.

AB - For the first time, a 1H solid-state photo-CIDNP effect is reported. The effect is observed in frozen solution of cyclohexanone in 1,4-dioxane-d8 under magic-angle spinning and continuous irradiation by the full spectrum of a xenon arc lamp. The spectral features show close similarity with those observed by 1H liquid-state photo-CIDNP NMR.

KW - aliphatic ketones

KW - Biradicals

KW - exchange interaction

KW - hyperpolarisation

KW - magic-angle spinning

KW - MAS

KW - norrish type I photo-reaction

KW - PHOTOSYNTHETIC REACTION CENTERS

KW - BACTERIA

KW - MECHANISM

KW - ELECTRON-DONOR

KW - MAGNETIC-FIELD DEPENDENCE

KW - PHASE

KW - DYNAMIC NUCLEAR-POLARIZATION

KW - BIRADICALS

KW - MAS NMR

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U2 - 10.1080/00268976.2018.1512722

DO - 10.1080/00268976.2018.1512722

M3 - Article

AN - SCOPUS:85071370928

VL - 117

SP - 2756

EP - 2761

JO - Molecular Physics

JF - Molecular Physics

SN - 0026-8976

IS - 19

ER -