Rice Husk Derived Micro-Mesoporous Carbon Materials as Active Components of Supercapacitor Electrodes

M. V. Lebedeva, P. M. Yeletsky, A. B. Ayupov, A. N. Kuznetsov, E. N. Gribov, V. N. Parmon

Результат исследования: Научные публикации в периодических изданияхстатья

4 Цитирования (Scopus)

Аннотация

Activated carbon materials (CM) were prepared from rice husk carbonized in the fluidized catalysts bed reactor. Textural characteristics of CM were studied by the adsorption of nitrogen at 77 K. Variation of synthesis conditions (conditions of carbonization and following activation) allowed to obtain materials with specific BET surface area from 440 to 2290 m2/g. Utilization of sodium or potassium carbonates results in the BET surface area up to 1200 m2/g. Activation by hydroxides of sodium or potassium yields the samples with the more developed surface up to 2290 m2/g. Electrochemical properties and capacitive characteristics were examined by cyclic voltammetry and chronopotentiometry in galvanostatic mode in aqueous electrolyte 1 M H2SO4 and ionic liquid BMIMBF4. It was shown, that at low charge/discharge rate (0.2 А/g) gravimetric capacitance depends linearly on specific surface of CM and does not depend on electrolyte nature. Insignificant (in the case of 1 М H2SO4) and significant (in the case of ionic liquid) decrease of specific capacitance is observed at high rates of charge/discharge (2 А/g), which is explained by influence of porous structure.

Язык оригиналаанглийский
Страницы (с-по)173-180
Число страниц8
ЖурналCatalysis in Industry
Том10
Номер выпуска2
DOI
СостояниеОпубликовано - 1 апр 2018

Fingerprint Подробные сведения о темах исследования «Rice Husk Derived Micro-Mesoporous Carbon Materials as Active Components of Supercapacitor Electrodes». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать