@article{0b9bf5da98db44df9caa8de27afb2b30,
title = "Rh- and Rh–Ni–MgO-based structured catalysts for on-board syngas production via gasoline processing",
abstract = "Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl and Rh/Ni–MgO/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl FeCrAlloy wire mesh supported catalysts were prepared via multistep procedure. They were characterized by XRD, SEM and TEM techniques. A comparative study of autothermal reforming (ATR) of isooctane and simulated gasoline (blends of isooctane, ortho-xylene and naphthalene) over Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl and Rh/Ni–MgO/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl was performed. Both catalysts showed excellent performance in ATR of isooctane at molar ratios of O2:C = 0.51 and H2O:C = 2.59, T = 750°С and GHSV = 10000 h−1. In the ATR of isooctane – o-xylene blend in presence of Rh–Ni-containing catalyst carbon formation was observed. Rh-containing catalyst demonstrated rather good activity and stability even in the case of isooctane – o-xylene – naphthalene blend.",
keywords = "Autothermal reforming, Gasoline, Isooctane, Nickel, Rhodium, Syngas",
author = "Ruban, {N. V.} and Potemkin, {D. I.} and Rogozhnikov, {V. N.} and Shefer, {K. I.} and Snytnikov, {P. V.} and Sobyanin, {V. A.}",
note = "Funding Information: In the part of catalyst characterization and experiments with aromatic compounds, the work was supported by the Russian Science Foundation under the project № 19-19-00257 . In the part of experiments with pure isooctane the work was supported by Russian Foundation for Basic Research under the project № 20-33-90162 (N.V. Ruban). The experiments were carried out using facilities of the shared research center “National center of investigation of catalysts” at Boreskov Institute of Catalysis. Publisher Copyright: {\textcopyright} 2021 Hydrogen Energy Publications LLC Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = feb,
day = "25",
doi = "10.1016/j.ijhydene.2021.01.183",
language = "English",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Ltd",
}