Redetermination of the crystal structure of the 2D heterometallic framework prepared from [Ni(cyclam)]2+ and [Re(CN)7]3-

Taisiya S. Sukhikh, Kira E. Vostrikova

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

A new XRD experiment and crystal structure refinement was performed for the earlier published compound in the paper “Heterobimetallic coordination polymers involving 3d metal complexes and heavier transition metals cyanometallates” by Peresypkina et al. (2015) [1]. A choice of a crystal cell taking in consideration the superstructural reflections allowed to obtain more reliable data about the symmetry and bond distances in the heterometallic 2D framework {[Ni(cyclam)]2[ReO(OH)0.5(MeOH)0.5(CN)4]}2.5+. Additionally, doubling of the parameter c permitted to get more details about interlayer space. As a result, disordered perchlorate anions and solvate molecules were located.

Язык оригиналаанглийский
Страницы (с-по)485-487
Число страниц3
ЖурналJournal of Solid State Chemistry
Том258
DOI
СостояниеОпубликовано - 1 фев 2018

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