Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior

E. V. Korneeva, O. V. Loseva, A. I. Smolentsev, A. V. Ivanov

Результат исследования: Научные публикации в периодических изданияхстатья

1 Цитирования (Scopus)

Аннотация

New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2])n; the second complex consists of isomeric cations, linear [AgCl2] anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).

Язык оригиналаанглийский
Страницы (с-по)1681-1689
Число страниц9
ЖурналRussian Journal of General Chemistry
Том88
Номер выпуска8
DOI
СостояниеОпубликовано - 1 авг 2018

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