Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior

E. V. Korneeva; O. V. Loseva; A. I. Smolentsev; A. V. Ivanov

doi:10.1134/S1070363218080200

Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S₂CNEt₂)₂][AgCl₂]}_n and {[Au(S₂CNEt₂)₂]₂[AgCl₂]Cl·2H₂O}_n: Synthesis, Supramolecular Structures, and Thermal Behavior

E. V. Korneeva, O. V. Loseva, A. I. Smolentsev, A. V. Ivanov

Лаборатория полиядерных координационных соединений ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

New ion polymeric gold(III)–silver(I) complexes, {[Au(S₂CNEt₂)₂][AgCl₂]}_n and {[Au(S₂CNEt₂)₂]₂[AgCl₂]Cl·2H₂O}_n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S₂CNEt₂}₂]⁺ complex cations and polymeric silver chloride anion ([AgCl₂]^–)_n; the second complex consists of isomeric cations, linear [AgCl₂]^– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).

Язык оригинала	английский
Страницы (с-по)	1681-1689
Число страниц	9
Журнал	Russian Journal of General Chemistry
Том	88
Номер выпуска	8
DOI	https://doi.org/10.1134/S1070363218080200
Состояние	Опубликовано - 1 авг. 2018

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10.1134/S1070363218080200

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Korneeva, E. V., Loseva, O. V., Smolentsev, A. I., & Ivanov, A. V. (2018). Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S₂CNEt₂)₂][AgCl₂]}_n and {[Au(S₂CNEt₂)₂]₂[AgCl₂]Cl·2H₂O}_n: Synthesis, Supramolecular Structures, and Thermal Behavior. Russian Journal of General Chemistry, 88(8), 1681-1689. https://doi.org/10.1134/S1070363218080200

@article{b0a439358ede461bb6d5a8105347167f,

title = "Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior",

abstract = "New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2]–)n; the second complex consists of isomeric cations, linear [AgCl2]– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).",

keywords = "gold(III)–silver(I) complexes, ion polymeric complexes, ligand exchange, Silver(I) dithiocarbamates, supramolecular self-organization, HETEROPOLYNUCLEAR COMPLEX, HEXAMER, CHEMISORPTION, ISO-C3H7, MOLECULAR-STRUCTURE, CRYSTAL-STRUCTURE, ANTIBACTERIAL, SELF-ORGANIZATION, ANTITUMOR-ACTIVITY, gold(III)-silver(I) complexes, GOLD(III)",

author = "Korneeva, {E. V.} and Loseva, {O. V.} and Smolentsev, {A. I.} and Ivanov, {A. V.}",

year = "2018",

month = aug,

day = "1",

doi = "10.1134/S1070363218080200",

language = "English",

volume = "88",

pages = "1681--1689",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "8",

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Korneeva, EV, Loseva, OV, Smolentsev, AI & Ivanov, AV 2018, 'Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S₂CNEt₂)₂][AgCl₂]}_n and {[Au(S₂CNEt₂)₂]₂[AgCl₂]Cl·2H₂O}_n: Synthesis, Supramolecular Structures, and Thermal Behavior', Russian Journal of General Chemistry, том. 88, № 8, стр. 1681-1689. https://doi.org/10.1134/S1070363218080200

Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S₂CNEt₂)₂][AgCl₂]}_n and {[Au(S₂CNEt₂)₂]₂[AgCl₂]Cl·2H₂O}_n : Synthesis, Supramolecular Structures, and Thermal Behavior. / Korneeva, E. V.; Loseva, O. V.; Smolentsev, A. I. и др.

В: Russian Journal of General Chemistry, Том 88, № 8, 01.08.2018, стр. 1681-1689.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n

T2 - Synthesis, Supramolecular Structures, and Thermal Behavior

AU - Korneeva, E. V.

AU - Loseva, O. V.

AU - Smolentsev, A. I.

AU - Ivanov, A. V.

PY - 2018/8/1

Y1 - 2018/8/1

N2 - New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2]–)n; the second complex consists of isomeric cations, linear [AgCl2]– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).

AB - New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2]–)n; the second complex consists of isomeric cations, linear [AgCl2]– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA).

KW - gold(III)–silver(I) complexes

KW - ion polymeric complexes

KW - ligand exchange

KW - Silver(I) dithiocarbamates

KW - supramolecular self-organization

KW - HETEROPOLYNUCLEAR COMPLEX

KW - HEXAMER

KW - CHEMISORPTION

KW - ISO-C3H7

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL-STRUCTURE

KW - ANTIBACTERIAL

KW - SELF-ORGANIZATION

KW - ANTITUMOR-ACTIVITY

KW - gold(III)-silver(I) complexes

KW - GOLD(III)

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U2 - 10.1134/S1070363218080200

DO - 10.1134/S1070363218080200

M3 - Article

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VL - 88

SP - 1681

EP - 1689

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

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