REACTION OF SEVERAL RESVERATROL GLYCOSIDE DERIVATIVES WITH HYPOCHLORITES IN VARIOUS MEDIA

A. D. Rogachev, N. I. Komarova, A. V. Pozdeeva, D. V. Korchagina, V. G. Vasil'ev, N. F. Salakhutdinov, G. A. Tolstikov

Результат исследования: Научные публикации в периодических изданияхстатьярецензирование

Аннотация

The reactions of pterostilbenoside (trans-3,5-dimethoxystilben-4'-O-beta-D-glucoside) and Ar-O-Tr derivatives of resveratroloside (3,5-dihydroxystilben-4'-O-beta-D-glucoside) and pinostilbenoside (3-methoxy-5-hydroxystilben-4'-O-beta-D-glucoside) with NaOCl and t-BuOCl in the presence of the stable nitroxyl radical TEMPO were studied in various media. It was found that the principal product of pterostilbenoside transformation was its 2,6-dichloroderivative, a part of which was oxidized to form 2,6-dichloropterostilbene glucuronide. Trityl ethers of resveratroloside and pinostilbenoside reacted with the hypochlorites to form mixtures of products.

Язык оригиналаанглийский
Страницы (с-по)1-7
Число страниц7
ЖурналChemistry of Natural Compounds
Том48
Номер выпуска1
DOI
СостояниеОпубликовано - мар 2012

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