TY - JOUR
T1 - Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate
AU - Yambulatov, Dmitriy S.
AU - Petrov, Pavel A.
AU - Nelyubina, Yulia V.
AU - Starikova, Alyona A.
AU - Pavlov, Alexander A.
AU - Aleshin, Dmitry Yu
AU - Nikolaevskii, Stanislav A.
AU - Kiskin, Mikhail A.
AU - Sokolov, Maxim N.
AU - Eremenko, Igor L.
PY - 2020/5/1
Y1 - 2020/5/1
N2 - An adduct of ZnII pivalate with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene has been prepared and characterized by X-ray diffraction analysis, NMR spectroscopy and DFT calculations. The compound preserves mononuclear structure in solution and does not switch the coordination mode from normal to abnormal.
AB - An adduct of ZnII pivalate with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene has been prepared and characterized by X-ray diffraction analysis, NMR spectroscopy and DFT calculations. The compound preserves mononuclear structure in solution and does not switch the coordination mode from normal to abnormal.
KW - carboxylate complexes
KW - DFT calculations
KW - N-heterocyclic carbenes
KW - X-ray crystallography
KW - zinc(II)
UR - http://www.scopus.com/inward/record.url?scp=85085941969&partnerID=8YFLogxK
U2 - 10.1016/j.mencom.2020.05.010
DO - 10.1016/j.mencom.2020.05.010
M3 - Article
AN - SCOPUS:85085941969
VL - 30
SP - 293
EP - 295
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 3
ER -