Radical polymerization of radical-labeled monomers: The triarylmethyl-based radical monomer as an example

Mariya V. Edeleva, Sylvain R.A. Marque, Olga Yu Rogozhnikova, Victor M. Tormyshev, Tatiana I. Troitskaya, Elena G. Bagryanskaya

Результат исследования: Научные публикации в периодических изданияхстатья

3 Цитирования (Scopus)

Аннотация

Recent development of spin-labeled nitroxide-mediated polymerization (NMP) involving successful polymer preparation with high livingness and narrow dispersity in the presence of persistent trityl-based stable radicals attached to the initiators (90% recovery of a trityl radical signal after the polymerization) led us to the preparation of stable organic radical polymers based on trityl radical-substituted monomers using NMP as the method of polymerization despite the claims in the literature about its expected failure. Here, we present successful radical polymerization and NMP of a trityl radical-based tri- and mono-monomer yielding more than 90% recovery of the trityl radical signal.

Язык оригиналаанглийский
Страницы (с-по)2656-2664
Число страниц9
ЖурналJournal of Polymer Science, Part A: Polymer Chemistry
Том56
Номер выпуска23
DOI
СостояниеОпубликовано - 1 дек 2018

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