Аннотация
Recent development of spin-labeled nitroxide-mediated polymerization (NMP) involving successful polymer preparation with high livingness and narrow dispersity in the presence of persistent trityl-based stable radicals attached to the initiators (90% recovery of a trityl radical signal after the polymerization) led us to the preparation of stable organic radical polymers based on trityl radical-substituted monomers using NMP as the method of polymerization despite the claims in the literature about its expected failure. Here, we present successful radical polymerization and NMP of a trityl radical-based tri- and mono-monomer yielding more than 90% recovery of the trityl radical signal.
Язык оригинала | английский |
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Страницы (с-по) | 2656-2664 |
Число страниц | 9 |
Журнал | Journal of Polymer Science, Part A: Polymer Chemistry |
Том | 56 |
Номер выпуска | 23 |
DOI | |
Состояние | Опубликовано - 1 дек 2018 |