Аннотация
For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independent stages of CH4 transformation on Ni/support interface producing syngas with participation of support oxygen bridging species (the rate-limiting stage) and fast reoxidation of support sites by CO2 yielding CO regenerating reactive oxygen species.
Язык оригинала | английский |
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Номер статьи | 268 |
Число страниц | 11 |
Журнал | Catalysts |
Том | 7 |
Номер выпуска | 9 |
DOI | |
Состояние | Опубликовано - 12 сен 2017 |