Prereforming of Arctic Diesel Fuel into Syngas

A. V. Samoilov; V. A. Kirillov; A. B. Shigarov; A. S. Brayko; D. I. Potemkin; T. B. Shoinkhorova; P. V. Snytnikov; S. I. Uskov; A. A. Pechenkin; V. D. Belyaev; V. A. Sobyanin

doi:10.1134/S207005041804013X

Prereforming of Arctic Diesel Fuel into Syngas

A. V. Samoilov, V. A. Kirillov, A. B. Shigarov, A. S. Brayko, D. I. Potemkin, T. B. Shoinkhorova, P. V. Snytnikov, S. I. Uskov, A. A. Pechenkin, V. D. Belyaev, V. A. Sobyanin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

The possibility of using arctic low-sulfur diesel fuel for the production of syngas suitable for solid-oxide fuel cells (SOFSs) in a single stage via the prereforming reaction over Ni-MgO structured catalysts based on a highly porous cellular foam material (HPCFM) made of nickel is demonstrated. Catalysts with mass compositions (wt %) 10.7NiO–10MgO/HPCFM and 20NiO–10MgO/HPCFM are prepared, and their properties in the prereforming of arctic diesel fuel at 550°C are studied. The microstructure of the coating of these catalysts is studied via transmission electron microscopy (TEM) before and after the reaction. The resistance of these prereforming catalysts to carbonization is revealed to be the key factor influencing their stability under operation. The kinetic parameters of this reaction are determined. The obtained results could be helpful in creating power generation units based on fuel cells operating on arctic diesel fuel under the conditions of the Far North.

Язык оригинала	английский
Страницы (с-по)	321-327
Число страниц	7
Журнал	Catalysis in Industry
Том	10
Номер выпуска	4
DOI	https://doi.org/10.1134/S207005041804013X
Состояние	Опубликовано - 1 окт 2018

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10.1134/S207005041804013X

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title = "Prereforming of Arctic Diesel Fuel into Syngas",

abstract = "The possibility of using arctic low-sulfur diesel fuel for the production of syngas suitable for solid-oxide fuel cells (SOFSs) in a single stage via the prereforming reaction over Ni-MgO structured catalysts based on a highly porous cellular foam material (HPCFM) made of nickel is demonstrated. Catalysts with mass compositions (wt %) 10.7NiO–10MgO/HPCFM and 20NiO–10MgO/HPCFM are prepared, and their properties in the prereforming of arctic diesel fuel at 550°C are studied. The microstructure of the coating of these catalysts is studied via transmission electron microscopy (TEM) before and after the reaction. The resistance of these prereforming catalysts to carbonization is revealed to be the key factor influencing their stability under operation. The kinetic parameters of this reaction are determined. The obtained results could be helpful in creating power generation units based on fuel cells operating on arctic diesel fuel under the conditions of the Far North.",

keywords = "diesel, magnesium oxide, nickel, prereforming, syngas, LIQUID HYDROCARBONS, METHANE, CATALYST",

author = "Samoilov, {A. V.} and Kirillov, {V. A.} and Shigarov, {A. B.} and Brayko, {A. S.} and Potemkin, {D. I.} and Shoinkhorova, {T. B.} and Snytnikov, {P. V.} and Uskov, {S. I.} and Pechenkin, {A. A.} and Belyaev, {V. D.} and Sobyanin, {V. A.}",

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Prereforming of Arctic Diesel Fuel into Syngas. / Samoilov, A. V.; Kirillov, V. A.; Shigarov, A. B.; Brayko, A. S.; Potemkin, D. I.; Shoinkhorova, T. B.; Snytnikov, P. V.; Uskov, S. I.; Pechenkin, A. A.; Belyaev, V. D.; Sobyanin, V. A.

В: Catalysis in Industry, Том 10, № 4, 01.10.2018, стр. 321-327.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Prereforming of Arctic Diesel Fuel into Syngas

AU - Samoilov, A. V.

AU - Kirillov, V. A.

AU - Shigarov, A. B.

AU - Brayko, A. S.

AU - Potemkin, D. I.

AU - Shoinkhorova, T. B.

AU - Snytnikov, P. V.

AU - Uskov, S. I.

AU - Pechenkin, A. A.

AU - Belyaev, V. D.

AU - Sobyanin, V. A.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - The possibility of using arctic low-sulfur diesel fuel for the production of syngas suitable for solid-oxide fuel cells (SOFSs) in a single stage via the prereforming reaction over Ni-MgO structured catalysts based on a highly porous cellular foam material (HPCFM) made of nickel is demonstrated. Catalysts with mass compositions (wt %) 10.7NiO–10MgO/HPCFM and 20NiO–10MgO/HPCFM are prepared, and their properties in the prereforming of arctic diesel fuel at 550°C are studied. The microstructure of the coating of these catalysts is studied via transmission electron microscopy (TEM) before and after the reaction. The resistance of these prereforming catalysts to carbonization is revealed to be the key factor influencing their stability under operation. The kinetic parameters of this reaction are determined. The obtained results could be helpful in creating power generation units based on fuel cells operating on arctic diesel fuel under the conditions of the Far North.

AB - The possibility of using arctic low-sulfur diesel fuel for the production of syngas suitable for solid-oxide fuel cells (SOFSs) in a single stage via the prereforming reaction over Ni-MgO structured catalysts based on a highly porous cellular foam material (HPCFM) made of nickel is demonstrated. Catalysts with mass compositions (wt %) 10.7NiO–10MgO/HPCFM and 20NiO–10MgO/HPCFM are prepared, and their properties in the prereforming of arctic diesel fuel at 550°C are studied. The microstructure of the coating of these catalysts is studied via transmission electron microscopy (TEM) before and after the reaction. The resistance of these prereforming catalysts to carbonization is revealed to be the key factor influencing their stability under operation. The kinetic parameters of this reaction are determined. The obtained results could be helpful in creating power generation units based on fuel cells operating on arctic diesel fuel under the conditions of the Far North.

KW - diesel

KW - magnesium oxide

KW - nickel

KW - prereforming

KW - syngas

KW - LIQUID HYDROCARBONS

KW - METHANE

KW - CATALYST

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U2 - 10.1134/S207005041804013X

DO - 10.1134/S207005041804013X

M3 - Article

AN - SCOPUS:85060173753

VL - 10

SP - 321

EP - 327

JO - Catalysis in Industry

JF - Catalysis in Industry

SN - 2070-0504

IS - 4

ER -

Prereforming of Arctic Diesel Fuel into Syngas

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