Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers

Mehdi Elsayed Moussa; Michael Seidl; Gábor Balázs; Manfred Zabel; Alexander V. Virovets; Bianca Attenberger; Andrea Schreiner; Manfred Scheer

doi:10.1002/chem.201704582

Preorganized Ag^I Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers

Mehdi Elsayed Moussa, Michael Seidl, Gábor Balázs, Manfred Zabel, Alexander V. Virovets, Bianca Attenberger, Andrea Schreiner, Manfred Scheer

Лаборатория методов исследования состава и структуры функциональных материалов ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья

9 Цитирования (Scopus)

Аннотация

An Ag^I dimer capped with labile organometallic diphosphorus ligands [Cp₂Mo₂(CO)₄(η²-P₂)] (Cp=C₅H₅) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic–organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.

Язык оригинала	английский
Страницы (с-по)	16199-16203
Число страниц	5
Журнал	Chemistry - A European Journal
Том	23
Номер выпуска	64
DOI	https://doi.org/10.1002/chem.201704582
Состояние	Опубликовано - 16 ноя 2017

Доступ к документу

10.1002/chem.201704582

Link to publication in Scopus

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Цитировать

Moussa, M. E., Seidl, M., Balázs, G., Zabel, M., Virovets, A. V., Attenberger, B., Schreiner, A., & Scheer, M. (2017). Preorganized Ag^I Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers. Chemistry - A European Journal, 23(64), 16199-16203. https://doi.org/10.1002/chem.201704582

Moussa, Mehdi Elsayed ; Seidl, Michael ; Balázs, Gábor ; Zabel, Manfred ; Virovets, Alexander V. ; Attenberger, Bianca ; Schreiner, Andrea ; Scheer, Manfred. / Preorganized Ag^I Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers. В: Chemistry - A European Journal. 2017 ; Том 23, № 64. стр. 16199-16203.

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abstract = "An AgI dimer capped with labile organometallic diphosphorus ligands [Cp2Mo2(CO)4(η2-P2)] (Cp=C5H5) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic–organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.",

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Preorganized Ag^I Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers. / Moussa, Mehdi Elsayed; Seidl, Michael; Balázs, Gábor; Zabel, Manfred; Virovets, Alexander V.; Attenberger, Bianca; Schreiner, Andrea; Scheer, Manfred.

В: Chemistry - A European Journal, Том 23, № 64, 16.11.2017, стр. 16199-16203.

Результат исследования: Научные публикации в периодических изданиях › статья

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AU - Moussa, Mehdi Elsayed

AU - Seidl, Michael

AU - Balázs, Gábor

AU - Zabel, Manfred

AU - Virovets, Alexander V.

AU - Attenberger, Bianca

AU - Schreiner, Andrea

AU - Scheer, Manfred

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KW - SUPRAMOLECULAR ASSEMBLIES

KW - PENTAPHOSPHAFERROCENE

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KW - METALLACYCLES

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