Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers

Mehdi Elsayed Moussa, Michael Seidl, Gábor Balázs, Manfred Zabel, Alexander V. Virovets, Bianca Attenberger, Andrea Schreiner, Manfred Scheer

Результат исследования: Научные публикации в периодических изданияхстатья

9 Цитирования (Scopus)

Аннотация

An AgI dimer capped with labile organometallic diphosphorus ligands [Cp2Mo2(CO)42-P2)] (Cp=C5H5) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic–organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.

Язык оригиналаанглийский
Страницы (с-по)16199-16203
Число страниц5
ЖурналChemistry - A European Journal
Том23
Номер выпуска64
DOI
СостояниеОпубликовано - 16 ноя 2017

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  • Цитировать

    Moussa, M. E., Seidl, M., Balázs, G., Zabel, M., Virovets, A. V., Attenberger, B., Schreiner, A., & Scheer, M. (2017). Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers. Chemistry - A European Journal, 23(64), 16199-16203. https://doi.org/10.1002/chem.201704582