Аннотация
The tailored synthesis of periodic coordination structures is fundamentally important for the design of porous compounds with desired functionalities. The building block approach allows a rational and modular design of metal-organic frameworks to be accomplished from the scratch. This concept takes the advantage of the structural robustness and fixed geometry of ligands in the pre-synthesized complexes. Moreover, such a synthetic protocol can lead to otherwise unaccessible coordination structures. This review outlines the examples of the successful creation of metal-organic frameworks from discrete polynuclear complexes. We hope this work will inspire researchers in their everlasting quest for the targeted design of the materials with desired functionalities.
Язык оригинала | английский |
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Страницы (с-по) | 321-331 |
Число страниц | 11 |
Журнал | Mendeleev Communications |
Том | 27 |
Номер выпуска | 4 |
DOI | |
Состояние | Опубликовано - 1 июл 2017 |