Аннотация
The reaction of [(DippForm)2Ln(thf)2] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (LnnSx) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S8 with divalent lanthanides.
Язык оригинала | английский |
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Страницы (с-по) | 13249-13252 |
Число страниц | 4 |
Журнал | Angewandte Chemie - International Edition |
Том | 56 |
Номер выпуска | 43 |
DOI | |
Состояние | Опубликовано - 16 окт 2017 |