Polysulfide Coordination Clusters of the Lanthanides

Ying Zhao Ma; Sebastian Bestgen; Michael T. Gamer; Sergey N. Konchenko; Peter W. Roesky

doi:10.1002/anie.201707578

Polysulfide Coordination Clusters of the Lanthanides

Ying Zhao Ma, Sebastian Bestgen, Michael T. Gamer, Sergey N. Konchenko, Peter W. Roesky

Результат исследования: Научные публикации в периодических изданиях › статья

18 Цитирования (Scopus)

Аннотация

The reaction of [(DippForm)₂Ln(thf)₂] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)₃Ln₃S₁₂] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (Ln_nS_x) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S₈ with divalent lanthanides.

Язык оригинала	английский
Страницы (с-по)	13249-13252
Число страниц	4
Журнал	Angewandte Chemie - International Edition
Том	56
Номер выпуска	43
DOI	https://doi.org/10.1002/anie.201707578
Состояние	Опубликовано - 16 окт 2017

Доступ к документу

10.1002/anie.201707578

Link to publication in Scopus

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Цитировать

Ma, Y. Z., Bestgen, S., Gamer, M. T., Konchenko, S. N., & Roesky, P. W. (2017). Polysulfide Coordination Clusters of the Lanthanides. Angewandte Chemie - International Edition, 56(43), 13249-13252. https://doi.org/10.1002/anie.201707578

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title = "Polysulfide Coordination Clusters of the Lanthanides",

abstract = "The reaction of [(DippForm)2Ln(thf)2] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (LnnSx) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S8 with divalent lanthanides.",

keywords = "coordination clusters, lanthanides, samarium, sulfur, ytterbium",

author = "Ma, {Ying Zhao} and Sebastian Bestgen and Gamer, {Michael T.} and Konchenko, {Sergey N.} and Roesky, {Peter W.}",

year = "2017",

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Polysulfide Coordination Clusters of the Lanthanides. / Ma, Ying Zhao; Bestgen, Sebastian; Gamer, Michael T.; Konchenko, Sergey N.; Roesky, Peter W.

В: Angewandte Chemie - International Edition, Том 56, № 43, 16.10.2017, стр. 13249-13252.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Polysulfide Coordination Clusters of the Lanthanides

AU - Ma, Ying Zhao

AU - Bestgen, Sebastian

AU - Gamer, Michael T.

AU - Konchenko, Sergey N.

AU - Roesky, Peter W.

PY - 2017/10/16

Y1 - 2017/10/16

N2 - The reaction of [(DippForm)2Ln(thf)2] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (LnnSx) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S8 with divalent lanthanides.

AB - The reaction of [(DippForm)2Ln(thf)2] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (LnnSx) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S8 with divalent lanthanides.

KW - coordination clusters

KW - lanthanides

KW - samarium

KW - sulfur

KW - ytterbium

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