Polysulfide Coordination Clusters of the Lanthanides

Ying Zhao Ma; Sebastian Bestgen; Michael T. Gamer; Sergey N. Konchenko; Peter W. Roesky

doi:10.1002/anie.201707578

Polysulfide Coordination Clusters of the Lanthanides

Ying Zhao Ma, Sebastian Bestgen, Michael T. Gamer, Sergey N. Konchenko, Peter W. Roesky

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

23 Цитирования (Scopus)

Аннотация

The reaction of [(DippForm)₂Ln(thf)₂] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)₃Ln₃S₁₂] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (Ln_nS_x) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S₈ with divalent lanthanides.

Язык оригинала	английский
Страницы (с-по)	13249-13252
Число страниц	4
Журнал	Angewandte Chemie - International Edition
Том	56
Номер выпуска	43
DOI	https://doi.org/10.1002/anie.201707578
Состояние	Опубликовано - 16 окт. 2017

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10.1002/anie.201707578

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@article{22374c8213b2424a9a459653c1fecb8b,

title = "Polysulfide Coordination Clusters of the Lanthanides",

abstract = "The reaction of [(DippForm)2Ln(thf)2] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (LnnSx) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S8 with divalent lanthanides.",

keywords = "coordination clusters, lanthanides, samarium, sulfur, ytterbium",

author = "Ma, {Ying Zhao} and Sebastian Bestgen and Gamer, {Michael T.} and Konchenko, {Sergey N.} and Roesky, {Peter W.}",

year = "2017",

month = oct,

day = "16",

doi = "10.1002/anie.201707578",

language = "English",

volume = "56",

pages = "13249--13252",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "43",

}

Polysulfide Coordination Clusters of the Lanthanides. / Ma, Ying Zhao; Bestgen, Sebastian; Gamer, Michael T. и др.

В: Angewandte Chemie - International Edition, Том 56, № 43, 16.10.2017, стр. 13249-13252.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Polysulfide Coordination Clusters of the Lanthanides

AU - Ma, Ying Zhao

AU - Bestgen, Sebastian

AU - Gamer, Michael T.

AU - Konchenko, Sergey N.

AU - Roesky, Peter W.

PY - 2017/10/16

Y1 - 2017/10/16

N2 - The reaction of [(DippForm)2Ln(thf)2] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (LnnSx) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S8 with divalent lanthanides.

AB - The reaction of [(DippForm)2Ln(thf)2] with an excess of elemental sulfur in toluene resulted in the formation of the trinuclear polysulfide coordination clusters [(DippForm)3Ln3S12] (Ln=Sm, Yb; DippForm=N,N′-bis(2,6-diisopropylphenyl)formamidinate). These are the first f element coordination clusters (LnnSx) with a larger polysulfide unit (n and x>2). The formation of the coordination clusters can be rationalized by the reductive cleavage of S8 with divalent lanthanides.

KW - coordination clusters

KW - lanthanides

KW - samarium

KW - sulfur

KW - ytterbium

UR - http://www.scopus.com/inward/record.url?scp=85031099880&partnerID=8YFLogxK

U2 - 10.1002/anie.201707578

DO - 10.1002/anie.201707578

M3 - Article

AN - SCOPUS:85031099880

VL - 56

SP - 13249

EP - 13252

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 43

ER -

Polysulfide Coordination Clusters of the Lanthanides

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