Polynuclear NiII and CoII hexafluoroacetylacetonates

O. V. Kuznetsova; E. Yu Fursova; G. A. Letyagin; G. V. Romanenko; V. I. Ovcharenko

doi:10.1007/s11172-018-2202-8

Polynuclear Ni^II and Co^II hexafluoroacetylacetonates

O. V. Kuznetsova, E. Yu Fursova, G. A. Letyagin, G. V. Romanenko, V. I. Ovcharenko

Физический факультет

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

2 Цитирования (Scopus)

Аннотация

Hydrolysis of [M₄(hfac)₄(MeO)₄(MeOH)₄] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni₇(hfac)₆(OH)₈(H₂O)₆]•2H₂O, [Co₁₂(hfac)₁₀(OH)₁₄(H₂O)₈]•2H₂O•2MePh, [Co₁₂(hfac)₁₀(OH)₁₄(H₂O)₄(Me₂CO)₄]•3PhMe, and [Co₁₂(hfac)₁₀(OH)₁₄(H₂O)₆(Me₂CO)₂]•2H₂O•2Me₂CO, whose structures were confirmed by X-ray analysis.

Язык оригинала	английский
Страницы (с-по)	1202-1205
Число страниц	4
Журнал	Russian Chemical Bulletin
Том	67
Номер выпуска	7
DOI	https://doi.org/10.1007/s11172-018-2202-8
Состояние	Опубликовано - 1 июл 2018

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10.1007/s11172-018-2202-8

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title = "Polynuclear NiII and CoII hexafluoroacetylacetonates",

abstract = "Hydrolysis of [M4(hfac)4(MeO)4(MeOH)4] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni7(hfac)6(OH)8(H2O)6]•2H2O, [Co12(hfac)10(OH)14(H2O)8]•2H2O•2MePh, [Co12(hfac)10(OH)14(H2O)4(Me2CO)4]•3PhMe, and [Co12(hfac)10(OH)14(H2O)6(Me2CO)2]•2H2O•2Me2CO, whose structures were confirmed by X-ray analysis.",

keywords = "cobalt(II), hexafluoroacetylacetonate, hydrolysis, nickel(II), polynuclear compounds, X-ray analysis, SINGLE-MOLECULE MAGNET, COMPLEXES",

author = "Kuznetsova, {O. V.} and Fursova, {E. Yu} and Letyagin, {G. A.} and Romanenko, {G. V.} and Ovcharenko, {V. I.}",

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Polynuclear Ni^II and Co^II hexafluoroacetylacetonates. / Kuznetsova, O. V.; Fursova, E. Yu; Letyagin, G. A.; Romanenko, G. V.; Ovcharenko, V. I.

В: Russian Chemical Bulletin, Том 67, № 7, 01.07.2018, стр. 1202-1205.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Polynuclear NiII and CoII hexafluoroacetylacetonates

AU - Kuznetsova, O. V.

AU - Fursova, E. Yu

AU - Letyagin, G. A.

AU - Romanenko, G. V.

AU - Ovcharenko, V. I.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - Hydrolysis of [M4(hfac)4(MeO)4(MeOH)4] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni7(hfac)6(OH)8(H2O)6]•2H2O, [Co12(hfac)10(OH)14(H2O)8]•2H2O•2MePh, [Co12(hfac)10(OH)14(H2O)4(Me2CO)4]•3PhMe, and [Co12(hfac)10(OH)14(H2O)6(Me2CO)2]•2H2O•2Me2CO, whose structures were confirmed by X-ray analysis.

AB - Hydrolysis of [M4(hfac)4(MeO)4(MeOH)4] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni7(hfac)6(OH)8(H2O)6]•2H2O, [Co12(hfac)10(OH)14(H2O)8]•2H2O•2MePh, [Co12(hfac)10(OH)14(H2O)4(Me2CO)4]•3PhMe, and [Co12(hfac)10(OH)14(H2O)6(Me2CO)2]•2H2O•2Me2CO, whose structures were confirmed by X-ray analysis.

KW - cobalt(II)

KW - hexafluoroacetylacetonate

KW - hydrolysis

KW - nickel(II)

KW - polynuclear compounds

KW - X-ray analysis

KW - SINGLE-MOLECULE MAGNET

KW - COMPLEXES

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U2 - 10.1007/s11172-018-2202-8

DO - 10.1007/s11172-018-2202-8

M3 - Article

AN - SCOPUS:85054187099

VL - 67

SP - 1202

EP - 1205

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 7