Polymeric Lead(II) Iodoacetate: Pb···I and I···I Non-Covalent Interactions in the Solid State

Sergey A. Adonin, Alexander S. Novikov, Maxim N. Sokolov

Результат исследования: Научные публикации в периодических изданияхстатья

2 Цитирования (Scopus)

Аннотация

Two-dimensional Pb II iodoacetate complex {Pb(ICH 2 COO) 2 } n (1) was prepared by reaction of lead nitrate with potassium iodoacetate. In 1, Pb is hepta-coordinated; additionally, metal centers participate in non-covalent I···I and Pb···I contacts. According to the analysis of XRD data and DFT calculations, the I···I non-covalent interactions are crystal packing-induced type I contacts, and Pb···I contacts are caused by interactions between Pb 2+ as electrophilic center and lone pairs of the iodine atom.

Язык оригиналаанглийский
Страницы (с-по)4221-4223
Число страниц3
ЖурналEuropean Journal of Inorganic Chemistry
Том2019
Номер выпуска39-40
DOI
СостояниеОпубликовано - 31 окт 2019

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