Polyfluorinated triphenyl-4,5-dihydro-1H-pyrazoles with dendroid arylsulfanyl moieties as donor blocks in donor-acceptor chromophores

Roman A. Ishchenko, Irina Yu Kargapolova, Natalia Orlova, Vladimir V. Shelkovnikov, Alexander Maksimov, Nikita D. Ryazanov, Viktoria N. Berezhnaya, Alexander Chernonosov

Результат исследования: Научные публикации в периодических изданияхстатьярецензирование

Аннотация

A series of novel donor-acceptor chromophores were synthesized using formylated derivatives of polyfluorinated triarylpyrazolines with branched moieties as donor blocks and dicyanoisophorone as acceptor. The nucleophilic substitution of fluorine with 4-hydroxypiperidine in decafluoropyrazoline was used to further functionalize the chromophore molecule. An existing method for introducing the dendroid moiety was improved. The properties of the final chromophores were estimated by DFT calculations.

Язык оригиналаанглийский
Номер статьи109841
ЖурналJournal of Fluorine Chemistry
Том248
DOI
СостояниеОпубликовано - авг 2021

Предметные области OECD FOS+WOS

  • 1.05 НАУКИ О ЗЕМЛЕ И СМЕЖНЫЕ ЭКОЛОГИЧЕСКИЕ НАУКИ
  • 1.06 БИОЛОГИЧЕСКИЕ НАУКИ
  • 1.04 ХИМИЧЕСКИЕ НАУКИ

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