Plasma-arc sputtering for synthesis of Pt/CeO2 and Pd/CeO2 nanosystems

E. A. Derevyannikova; T. Yu Kardash; A. I. Stadnichenko; E. M. Slavinskaya; A. V. Zaikovskii; S. A. Novopashin; A. I. Boronin

doi:10.1088/1742-6596/1124/2/022024

Plasma-arc sputtering for synthesis of Pt/CeO₂ and Pd/CeO₂ nanosystems

E. A. Derevyannikova, T. Yu Kardash, A. I. Stadnichenko, E. M. Slavinskaya, A. V. Zaikovskii, S. A. Novopashin, A. I. Boronin

Результат исследования: Научные публикации в периодических изданиях › статья по материалам конференции

Аннотация

Plasma-arc (PA) sputtering method was applied for synthesis of Pt/CeO₂ and Pd/CeO₂ nanoparticles. PA represents a joint sputtering of a graphite electrode with various metals (Ce with Pt or Pd). This novel approach allows obtaining highly dispersed metals and ceria on the first stage of synthesis. The thermal treatment of an initial composite in air at 600°C-1000°C results in the burnt of a carbon shell and formation of CeO₂ with a fluorite-type structure. XPS and TEM analysis showed that Pd and Pt species are stabilized in the ionic form due to strong interaction with ceria. Obtained nanoparticles have a high potential of application as catalysts for efficient low temperature CO oxidation.

Язык оригинала	английский
Номер статьи	022024
Журнал	Journal of Physics: Conference Series
Том	1124
Номер выпуска	2
DOI	https://doi.org/10.1088/1742-6596/1124/2/022024
Состояние	Опубликовано - 1 янв 2018
Событие	5th International School and Conference on Optoelectronics, Photonics, Engineering and Nanostructures, Saint Petersburg OPEN 2018 - St. Petersburg, Российская Федерация Продолжительность: 2 апр 2018 → 5 апр 2018

Доступ к документу

10.1088/1742-6596/1124/2/022024

Link to publication in Scopus

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Цитировать

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abstract = "Plasma-arc (PA) sputtering method was applied for synthesis of Pt/CeO2 and Pd/CeO2 nanoparticles. PA represents a joint sputtering of a graphite electrode with various metals (Ce with Pt or Pd). This novel approach allows obtaining highly dispersed metals and ceria on the first stage of synthesis. The thermal treatment of an initial composite in air at 600°C-1000°C results in the burnt of a carbon shell and formation of CeO2 with a fluorite-type structure. XPS and TEM analysis showed that Pd and Pt species are stabilized in the ionic form due to strong interaction with ceria. Obtained nanoparticles have a high potential of application as catalysts for efficient low temperature CO oxidation.",

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Plasma-arc sputtering for synthesis of Pt/CeO₂ and Pd/CeO₂ nanosystems. / Derevyannikova, E. A.; Kardash, T. Yu ; Stadnichenko, A. I.; Slavinskaya, E. M.; Zaikovskii, A. V.; Novopashin, S. A.; Boronin, A. I.

В: Journal of Physics: Conference Series, Том 1124, № 2, 022024, 01.01.2018.

Результат исследования: Научные публикации в периодических изданиях › статья по материалам конференции

TY - JOUR

T1 - Plasma-arc sputtering for synthesis of Pt/CeO2 and Pd/CeO2 nanosystems

AU - Derevyannikova, E. A.

AU - Kardash, T. Yu

AU - Stadnichenko, A. I.

AU - Slavinskaya, E. M.

AU - Zaikovskii, A. V.

AU - Novopashin, S. A.

AU - Boronin, A. I.

PY - 2018/1/1

Y1 - 2018/1/1

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AB - Plasma-arc (PA) sputtering method was applied for synthesis of Pt/CeO2 and Pd/CeO2 nanoparticles. PA represents a joint sputtering of a graphite electrode with various metals (Ce with Pt or Pd). This novel approach allows obtaining highly dispersed metals and ceria on the first stage of synthesis. The thermal treatment of an initial composite in air at 600°C-1000°C results in the burnt of a carbon shell and formation of CeO2 with a fluorite-type structure. XPS and TEM analysis showed that Pd and Pt species are stabilized in the ionic form due to strong interaction with ceria. Obtained nanoparticles have a high potential of application as catalysts for efficient low temperature CO oxidation.

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