Photochromism in oxalatoniobates

Alexandra A. Shmakova; Eugeniy M. Glebov; Valeri V. Korolev; Dmitri V. Stass; Enrico Benassi; Pavel A. Abramov; Maxim N. Sokolov

doi:10.1039/c7dt04077f

Photochromism in oxalatoniobates

Alexandra A. Shmakova, Eugeniy M. Glebov, Valeri V. Korolev, Dmitri V. Stass, Enrico Benassi, Pavel A. Abramov, Maxim N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

5 Цитирования (Scopus)

Аннотация

Addition of 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen) or 2-aminopyridine (2-NH₂-py) to aqueous solutions of (NH₄)[NbO(C₂O₄)₂(H₂O)₂]·3H₂O (Nb-Ox) yields tris-oxalate complexes (bpyH₂)(bpyH)[NbO(C₂O₄)₃]·2H₂O (1), (phenH)₃[NbO(C₂O₄)₃]·3H₂O (2), and (2-NH₂-pyH)₃[NbO(C₂O₄)₃]·2H₂O (3), which were characterised by XRD, IR and EA. Bipyridinium salt 1 demonstrates remarkable photoactivity even under irradiation by daylight. The nature of the photoactivity was studied by diffuse reflectance (DR) spectroscopy, ESR and quantum-chemical calculations.

Язык оригинала	английский
Страницы (с-по)	2247-2255
Число страниц	9
Журнал	Dalton Transactions
Том	47
Номер выпуска	7
DOI	https://doi.org/10.1039/c7dt04077f
Состояние	Опубликовано - 21 февр. 2018

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10.1039/c7dt04077f

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@article{4d1c34dc359747f8b801d9b8e4ad80da,

title = "Photochromism in oxalatoniobates",

abstract = "Addition of 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen) or 2-aminopyridine (2-NH2-py) to aqueous solutions of (NH4)[NbO(C2O4)2(H2O)2]·3H2O (Nb-Ox) yields tris-oxalate complexes (bpyH2)(bpyH)[NbO(C2O4)3]·2H2O (1), (phenH)3[NbO(C2O4)3]·3H2O (2), and (2-NH2-pyH)3[NbO(C2O4)3]·2H2O (3), which were characterised by XRD, IR and EA. Bipyridinium salt 1 demonstrates remarkable photoactivity even under irradiation by daylight. The nature of the photoactivity was studied by diffuse reflectance (DR) spectroscopy, ESR and quantum-chemical calculations.",

keywords = "EFFECTIVE CORE POTENTIALS, CRYSTAL-STRUCTURE, MOLECULAR CALCULATIONS, NIOBIUM OXIDE, PHOTOCHEMISTRY, OXALATE, CHEMISTRY, KINETICS, NB2O5, 4,4'-BIPYRIDINE",

author = "Shmakova, {Alexandra A.} and Glebov, {Eugeniy M.} and Korolev, {Valeri V.} and Stass, {Dmitri V.} and Enrico Benassi and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

month = feb,

day = "21",

doi = "10.1039/c7dt04077f",

language = "English",

volume = "47",

pages = "2247--2255",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "7",

}

TY - JOUR

T1 - Photochromism in oxalatoniobates

AU - Shmakova, Alexandra A.

AU - Glebov, Eugeniy M.

AU - Korolev, Valeri V.

AU - Stass, Dmitri V.

AU - Benassi, Enrico

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

PY - 2018/2/21

Y1 - 2018/2/21

N2 - Addition of 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen) or 2-aminopyridine (2-NH2-py) to aqueous solutions of (NH4)[NbO(C2O4)2(H2O)2]·3H2O (Nb-Ox) yields tris-oxalate complexes (bpyH2)(bpyH)[NbO(C2O4)3]·2H2O (1), (phenH)3[NbO(C2O4)3]·3H2O (2), and (2-NH2-pyH)3[NbO(C2O4)3]·2H2O (3), which were characterised by XRD, IR and EA. Bipyridinium salt 1 demonstrates remarkable photoactivity even under irradiation by daylight. The nature of the photoactivity was studied by diffuse reflectance (DR) spectroscopy, ESR and quantum-chemical calculations.

AB - Addition of 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen) or 2-aminopyridine (2-NH2-py) to aqueous solutions of (NH4)[NbO(C2O4)2(H2O)2]·3H2O (Nb-Ox) yields tris-oxalate complexes (bpyH2)(bpyH)[NbO(C2O4)3]·2H2O (1), (phenH)3[NbO(C2O4)3]·3H2O (2), and (2-NH2-pyH)3[NbO(C2O4)3]·2H2O (3), which were characterised by XRD, IR and EA. Bipyridinium salt 1 demonstrates remarkable photoactivity even under irradiation by daylight. The nature of the photoactivity was studied by diffuse reflectance (DR) spectroscopy, ESR and quantum-chemical calculations.

KW - EFFECTIVE CORE POTENTIALS

KW - CRYSTAL-STRUCTURE

KW - MOLECULAR CALCULATIONS

KW - NIOBIUM OXIDE

KW - PHOTOCHEMISTRY

KW - OXALATE

KW - CHEMISTRY

KW - KINETICS

KW - NB2O5

KW - 4,4'-BIPYRIDINE

UR - http://www.scopus.com/inward/record.url?scp=85042103181&partnerID=8YFLogxK

U2 - 10.1039/c7dt04077f

DO - 10.1039/c7dt04077f

M3 - Article

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AN - SCOPUS:85042103181

VL - 47

SP - 2247

EP - 2255

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 7

ER -

Photochromism in oxalatoniobates

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