Photocatalytic reaction of 4-cyanopyridine with tertiary amines

Aleksey Yu Vorob’ev

doi:10.1007/s10593-019-02423-7

Photocatalytic reaction of 4-cyanopyridine with tertiary amines

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

[Figure not available: see fulltext.] The reaction of 4-cyanopyridine with tertiary aliphatic amines photocatalyzed by fac-tris[2-phenylpyridinato-C ² ,N]iridium(III) complex was studied. The reactions led to arylation of the α-C–H bond of the amine to form the corresponding pyridin-4-yl derivatives along with unsubstituted pyridine.

Язык оригинала	английский
Страницы (с-по)	90-92
Число страниц	3
Журнал	Chemistry of Heterocyclic Compounds
Том	55
Номер выпуска	1
DOI	https://doi.org/10.1007/s10593-019-02423-7
Состояние	Опубликовано - 15 янв 2019

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10.1007/s10593-019-02423-7

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abstract = " [Figure not available: see fulltext.] The reaction of 4-cyanopyridine with tertiary aliphatic amines photocatalyzed by fac-tris[2-phenylpyridinato-C 2 ,N]iridium(III) complex was studied. The reactions led to arylation of the α-C–H bond of the amine to form the corresponding pyridin-4-yl derivatives along with unsubstituted pyridine. ",

keywords = "4-cyanopyridine, arylation, tertiary amines, visible-light photocatalysis, С–Н activation, FUNCTIONALIZATION, C-H activation, PHOTOREDOX CATALYSIS",

author = "Vorob{\textquoteright}ev, {Aleksey Yu}",

year = "2019",

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doi = "10.1007/s10593-019-02423-7",

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N2 - [Figure not available: see fulltext.] The reaction of 4-cyanopyridine with tertiary aliphatic amines photocatalyzed by fac-tris[2-phenylpyridinato-C 2 ,N]iridium(III) complex was studied. The reactions led to arylation of the α-C–H bond of the amine to form the corresponding pyridin-4-yl derivatives along with unsubstituted pyridine.

AB - [Figure not available: see fulltext.] The reaction of 4-cyanopyridine with tertiary aliphatic amines photocatalyzed by fac-tris[2-phenylpyridinato-C 2 ,N]iridium(III) complex was studied. The reactions led to arylation of the α-C–H bond of the amine to form the corresponding pyridin-4-yl derivatives along with unsubstituted pyridine.

KW - 4-cyanopyridine

KW - arylation

KW - tertiary amines

KW - visible-light photocatalysis

KW - С–Н activation

KW - FUNCTIONALIZATION

KW - C-H activation

KW - PHOTOREDOX CATALYSIS

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JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

SN - 0009-3122

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Photocatalytic reaction of 4-cyanopyridine with tertiary amines

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