[Pd(acac)(L)2][BF4] (L = morpholine, diethylamine, dibutylamine, dioctylamine): Synthesis, structure and their catalytic activity

D. S. Suslov; M. V. Bykov; G. V. Ratovskii; P. A. Abramov; M. V. Pahomova; I. A. Ushakov; V. K. Voronov; V. S. Tkach

doi:10.1016/j.molstruc.2016.12.025

[Pd(acac)(L)₂][BF₄] (L = morpholine, diethylamine, dibutylamine, dioctylamine): Synthesis, structure and their catalytic activity

D. S. Suslov, M. V. Bykov, G. V. Ratovskii, P. A. Abramov, M. V. Pahomova, I. A. Ushakov, V. K. Voronov, V. S. Tkach

Лаборатория функциональных материалов на основе кластеров и супрамолекулярных соединений ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

6 Цитирования (Scopus)

Аннотация

Cationic acetylacetonate bis(secondary amine) palladium (II) complexes were synthesized by nitrile substitution of [Pd(acac)(MeCN)₂][BF₄] with L (L = morpholine, diethylamine, dibutylamine, dioctylamine) which yielded [Pd(acac)(L)₂][BF₄] as a mononuclear species with chelating acac ligand. An X-ray diffraction, NMR, IR and DFT study of [Pd(acac){morpholine}₂][BF₄] establishes the presence of hydrogen bonding between the morpholine ligand and [BF₄]⁻ anion. Crystallographic defects in the crystal and presence of pseudocrystalline structure in solution of [Pd(acac){morpholine}₂][BF₄] were assumed to explain IR spectra features. Preliminary investigations into the polymerization of norbornene, dimerization of styrene, and telomerization of 1,3-butadiene with diethylamine were performed.

Язык оригинала	английский
Страницы (с-по)	411-421
Число страниц	11
Журнал	Journal of Molecular Structure
Том	1133
DOI	https://doi.org/10.1016/j.molstruc.2016.12.025
Состояние	Опубликовано - 5 апр 2017

Доступ к документу

10.1016/j.molstruc.2016.12.025

Link to publication in Scopus

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@article{aa5f752261c44073aa4183141145e18d,

title = "[Pd(acac)(L)2][BF4] (L = morpholine, diethylamine, dibutylamine, dioctylamine): Synthesis, structure and their catalytic activity",

abstract = "Cationic acetylacetonate bis(secondary amine) palladium (II) complexes were synthesized by nitrile substitution of [Pd(acac)(MeCN)2][BF4] with L (L = morpholine, diethylamine, dibutylamine, dioctylamine) which yielded [Pd(acac)(L)2][BF4] as a mononuclear species with chelating acac ligand. An X-ray diffraction, NMR, IR and DFT study of [Pd(acac){morpholine}2][BF4] establishes the presence of hydrogen bonding between the morpholine ligand and [BF4]− anion. Crystallographic defects in the crystal and presence of pseudocrystalline structure in solution of [Pd(acac){morpholine}2][BF4] were assumed to explain IR spectra features. Preliminary investigations into the polymerization of norbornene, dimerization of styrene, and telomerization of 1,3-butadiene with diethylamine were performed.",

keywords = "1,3-Butadiene, Acetylacetonate, Norbornene, Palladium, Secondary amine, Styrene, ALPHA-OLEFINS, TRANSITION-METAL-COMPLEXES, NICKEL(II) COMPLEXES, PALLADIUM(II)-ACETYLACETONATE COMPLEXES, ORDER REGULAR APPROXIMATION, ADDITION POLYMERIZATION, LIGANDS SYNTHESIS, BASIS-SETS, CATIONIC PALLADIUM(II) COMPOUNDS, SELECTIVE LINEAR DIMERIZATION",

author = "Suslov, {D. S.} and Bykov, {M. V.} and Ratovskii, {G. V.} and Abramov, {P. A.} and Pahomova, {M. V.} and Ushakov, {I. A.} and Voronov, {V. K.} and Tkach, {V. S.}",

year = "2017",

month = apr,

day = "5",

doi = "10.1016/j.molstruc.2016.12.025",

language = "English",

volume = "1133",

pages = "411--421",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier",

}

[Pd(acac)(L)₂][BF₄] (L = morpholine, diethylamine, dibutylamine, dioctylamine) : Synthesis, structure and their catalytic activity. / Suslov, D. S.; Bykov, M. V.; Ratovskii, G. V.; Abramov, P. A.; Pahomova, M. V.; Ushakov, I. A.; Voronov, V. K.; Tkach, V. S.

В: Journal of Molecular Structure, Том 1133, 05.04.2017, стр. 411-421.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - [Pd(acac)(L)2][BF4] (L = morpholine, diethylamine, dibutylamine, dioctylamine)

T2 - Synthesis, structure and their catalytic activity

AU - Suslov, D. S.

AU - Bykov, M. V.

AU - Ratovskii, G. V.

AU - Abramov, P. A.

AU - Pahomova, M. V.

AU - Ushakov, I. A.

AU - Voronov, V. K.

AU - Tkach, V. S.

PY - 2017/4/5

Y1 - 2017/4/5

N2 - Cationic acetylacetonate bis(secondary amine) palladium (II) complexes were synthesized by nitrile substitution of [Pd(acac)(MeCN)2][BF4] with L (L = morpholine, diethylamine, dibutylamine, dioctylamine) which yielded [Pd(acac)(L)2][BF4] as a mononuclear species with chelating acac ligand. An X-ray diffraction, NMR, IR and DFT study of [Pd(acac){morpholine}2][BF4] establishes the presence of hydrogen bonding between the morpholine ligand and [BF4]− anion. Crystallographic defects in the crystal and presence of pseudocrystalline structure in solution of [Pd(acac){morpholine}2][BF4] were assumed to explain IR spectra features. Preliminary investigations into the polymerization of norbornene, dimerization of styrene, and telomerization of 1,3-butadiene with diethylamine were performed.

AB - Cationic acetylacetonate bis(secondary amine) palladium (II) complexes were synthesized by nitrile substitution of [Pd(acac)(MeCN)2][BF4] with L (L = morpholine, diethylamine, dibutylamine, dioctylamine) which yielded [Pd(acac)(L)2][BF4] as a mononuclear species with chelating acac ligand. An X-ray diffraction, NMR, IR and DFT study of [Pd(acac){morpholine}2][BF4] establishes the presence of hydrogen bonding between the morpholine ligand and [BF4]− anion. Crystallographic defects in the crystal and presence of pseudocrystalline structure in solution of [Pd(acac){morpholine}2][BF4] were assumed to explain IR spectra features. Preliminary investigations into the polymerization of norbornene, dimerization of styrene, and telomerization of 1,3-butadiene with diethylamine were performed.

KW - 1,3-Butadiene

KW - Acetylacetonate

KW - Norbornene

KW - Palladium

KW - Secondary amine

KW - Styrene

KW - ALPHA-OLEFINS

KW - TRANSITION-METAL-COMPLEXES

KW - NICKEL(II) COMPLEXES

KW - PALLADIUM(II)-ACETYLACETONATE COMPLEXES

KW - ORDER REGULAR APPROXIMATION

KW - ADDITION POLYMERIZATION

KW - LIGANDS SYNTHESIS

KW - BASIS-SETS

KW - CATIONIC PALLADIUM(II) COMPOUNDS

KW - SELECTIVE LINEAR DIMERIZATION

UR - http://www.scopus.com/inward/record.url?scp=85006791159&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2016.12.025

DO - 10.1016/j.molstruc.2016.12.025

M3 - Article

AN - SCOPUS:85006791159

VL - 1133

SP - 411

EP - 421

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -