Particularities of low-temperature WGSR over ceramometal and oxide catalysts: Effect of catalyst particle size

S. F. Tikhov; T. P. Minyukova; S. I. Reshetnikov; K. R. Valeev; N. V. Vernikovskaya; A. N. Salanov; S. V. Cherepanova; V. A. Sadykov

doi:10.1016/j.cej.2019.05.089

Particularities of low-temperature WGSR over ceramometal and oxide catalysts: Effect of catalyst particle size

S. F. Tikhov, T. P. Minyukova, S. I. Reshetnikov, K. R. Valeev, N. V. Vernikovskaya, A. N. Salanov, S. V. Cherepanova, V. A. Sadykov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

1 Цитирования (Scopus)

Аннотация

Two types of the low temperature WGS catalysts were compared: oxide Cu-Zn-Al catalyst prepared through coprecipitation procedure and ceramometal CuAlO/CuA catalyst prepared from powdered CuAl alloy. The catalysts were characterized by XRD, SEM with EDX, adsorption-desorption isotherms. Activity was measured at a pressure of 1 bar in the mixture of CO:Н₂О:Н₂ = 8:42:50 at a steam/gas ratio of 0.6–0.7. The catalysts were used as a small (0.14–0.25 mm)and large (3.2 × 3.2 × 5 mm)fraction. It was found that oxide catalyst possesses of a developed mesopore structure with specific surface area 122 m²/g while ceramometal catalyst has a developed macropore structure with size up to ten microns and specific surface area 15.7 m²/g. As a result, large fraction (granules)of ceramometal catalyst has twofold higher effectiveness factor due to higher internal diffusion.

Язык оригинала	английский
Страницы (с-по)	405-411
Число страниц	7
Журнал	Chemical Engineering Journal
Том	374
DOI	https://doi.org/10.1016/j.cej.2019.05.089
Состояние	Опубликовано - 15 окт 2019
Опубликовано для внешнего пользования	Да

Доступ к документу

10.1016/j.cej.2019.05.089

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@article{98825f0512234589ab26f5fe8a04bd78,

title = "Particularities of low-temperature WGSR over ceramometal and oxide catalysts: Effect of catalyst particle size",

abstract = "Two types of the low temperature WGS catalysts were compared: oxide Cu-Zn-Al catalyst prepared through coprecipitation procedure and ceramometal CuAlO/CuA catalyst prepared from powdered CuAl alloy. The catalysts were characterized by XRD, SEM with EDX, adsorption-desorption isotherms. Activity was measured at a pressure of 1 bar in the mixture of CO:Н2О:Н2 = 8:42:50 at a steam/gas ratio of 0.6–0.7. The catalysts were used as a small (0.14–0.25 mm)and large (3.2 × 3.2 × 5 mm)fraction. It was found that oxide catalyst possesses of a developed mesopore structure with specific surface area 122 m2/g while ceramometal catalyst has a developed macropore structure with size up to ten microns and specific surface area 15.7 m2/g. As a result, large fraction (granules)of ceramometal catalyst has twofold higher effectiveness factor due to higher internal diffusion.",

keywords = "Effectiveness factor, Oxide and ceramometal catalysts, WGS reaction, METHANOL SYNTHESIS, OXIDATION, DESIGN, GAS SHIFT REACTION, STRUCTURE-SENSITIVITY",

author = "Tikhov, {S. F.} and Minyukova, {T. P.} and Reshetnikov, {S. I.} and Valeev, {K. R.} and Vernikovskaya, {N. V.} and Salanov, {A. N.} and Cherepanova, {S. V.} and Sadykov, {V. A.}",

year = "2019",

month = oct,

day = "15",

doi = "10.1016/j.cej.2019.05.089",

language = "English",

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journal = "Chemical Engineering Journal",

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Particularities of low-temperature WGSR over ceramometal and oxide catalysts : Effect of catalyst particle size. / Tikhov, S. F.; Minyukova, T. P.; Reshetnikov, S. I.; Valeev, K. R.; Vernikovskaya, N. V.; Salanov, A. N.; Cherepanova, S. V.; Sadykov, V. A.

В: Chemical Engineering Journal, Том 374, 15.10.2019, стр. 405-411.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Particularities of low-temperature WGSR over ceramometal and oxide catalysts

T2 - Effect of catalyst particle size

AU - Tikhov, S. F.

AU - Minyukova, T. P.

AU - Reshetnikov, S. I.

AU - Valeev, K. R.

AU - Vernikovskaya, N. V.

AU - Salanov, A. N.

AU - Cherepanova, S. V.

AU - Sadykov, V. A.

PY - 2019/10/15

Y1 - 2019/10/15

N2 - Two types of the low temperature WGS catalysts were compared: oxide Cu-Zn-Al catalyst prepared through coprecipitation procedure and ceramometal CuAlO/CuA catalyst prepared from powdered CuAl alloy. The catalysts were characterized by XRD, SEM with EDX, adsorption-desorption isotherms. Activity was measured at a pressure of 1 bar in the mixture of CO:Н2О:Н2 = 8:42:50 at a steam/gas ratio of 0.6–0.7. The catalysts were used as a small (0.14–0.25 mm)and large (3.2 × 3.2 × 5 mm)fraction. It was found that oxide catalyst possesses of a developed mesopore structure with specific surface area 122 m2/g while ceramometal catalyst has a developed macropore structure with size up to ten microns and specific surface area 15.7 m2/g. As a result, large fraction (granules)of ceramometal catalyst has twofold higher effectiveness factor due to higher internal diffusion.

AB - Two types of the low temperature WGS catalysts were compared: oxide Cu-Zn-Al catalyst prepared through coprecipitation procedure and ceramometal CuAlO/CuA catalyst prepared from powdered CuAl alloy. The catalysts were characterized by XRD, SEM with EDX, adsorption-desorption isotherms. Activity was measured at a pressure of 1 bar in the mixture of CO:Н2О:Н2 = 8:42:50 at a steam/gas ratio of 0.6–0.7. The catalysts were used as a small (0.14–0.25 mm)and large (3.2 × 3.2 × 5 mm)fraction. It was found that oxide catalyst possesses of a developed mesopore structure with specific surface area 122 m2/g while ceramometal catalyst has a developed macropore structure with size up to ten microns and specific surface area 15.7 m2/g. As a result, large fraction (granules)of ceramometal catalyst has twofold higher effectiveness factor due to higher internal diffusion.

KW - Effectiveness factor

KW - Oxide and ceramometal catalysts

KW - WGS reaction

KW - METHANOL SYNTHESIS

KW - OXIDATION

KW - DESIGN

KW - GAS SHIFT REACTION

KW - STRUCTURE-SENSITIVITY

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U2 - 10.1016/j.cej.2019.05.089

DO - 10.1016/j.cej.2019.05.089

M3 - Article

AN - SCOPUS:85066295528

VL - 374

SP - 405

EP - 411

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

SN - 1385-8947

ER -