Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts

S. D. Badmaev; N. O. Akhmetov; V. A. Sobyanin

doi:10.1007/s11244-019-01207-9

Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts

S. D. Badmaev, N. O. Akhmetov, V. A. Sobyanin

Результат исследования: Научные публикации в периодических изданиях › статья

2 Цитирования (Scopus)

Аннотация

Catalytic partial oxidation (PO) of dimethoxymethane (DMM) to syngas was investigated in a fixed-bed continuous flow reactor under ambient pressure and at 250–500 °C over Pt-, Rh- and Ru-supported on Ce_0.75Zr_0.25O_2–δ catalysts. The Pt catalyst was found to be the most active and selective. It provided complete conversion of DMM to gas mixture containing ˃ 60 vol% of H₂ and CO at 400 °C, GHSV = 10,000 h⁻¹ using a reaction mixture: DMM:O₂:N₂ = 28.6:14.3:57.1 (vol%).

Язык оригинала	английский
Страницы (с-по)	196-202
Число страниц	7
Журнал	Topics in Catalysis
Том	63
Номер выпуска	1-2
DOI	https://doi.org/10.1007/s11244-019-01207-9
Состояние	Опубликовано - 1 мар 2020

Доступ к документу

10.1007/s11244-019-01207-9

Link to publication in Scopus

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Цитировать

Badmaev, S. D., Akhmetov, N. O., & Sobyanin, V. A. (2020). Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts. Topics in Catalysis, 63(1-2), 196-202. https://doi.org/10.1007/s11244-019-01207-9

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abstract = "Catalytic partial oxidation (PO) of dimethoxymethane (DMM) to syngas was investigated in a fixed-bed continuous flow reactor under ambient pressure and at 250–500 °C over Pt-, Rh- and Ru-supported on Ce0.75Zr0.25O2–δ catalysts. The Pt catalyst was found to be the most active and selective. It provided complete conversion of DMM to gas mixture containing ˃ 60 vol% of H2 and CO at 400 °C, GHSV = 10,000 h−1 using a reaction mixture: DMM:O2:N2 = 28.6:14.3:57.1 (vol%).",

keywords = "Dimethoxymethane, Noble metal catalyst, Partial oxidation, Pt, SOFC, Syngas production, METHANOL, HYDROGEN-RICH GAS, RH, DIMETHYL ETHER, DECOMPOSITION",

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AU - Sobyanin, V. A.

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KW - Dimethoxymethane

KW - Noble metal catalyst

KW - Partial oxidation

KW - Pt

KW - SOFC

KW - Syngas production

KW - METHANOL

KW - HYDROGEN-RICH GAS

KW - RH

KW - DIMETHYL ETHER

KW - DECOMPOSITION

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