Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts

S. D. Badmaev; N. O. Akhmetov; V. A. Sobyanin

doi:10.1007/s11244-019-01207-9

Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts

S. D. Badmaev, N. O. Akhmetov, V. A. Sobyanin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

Catalytic partial oxidation (PO) of dimethoxymethane (DMM) to syngas was investigated in a fixed-bed continuous flow reactor under ambient pressure and at 250–500 °C over Pt-, Rh- and Ru-supported on Ce_0.75Zr_0.25O_2–δ catalysts. The Pt catalyst was found to be the most active and selective. It provided complete conversion of DMM to gas mixture containing ˃ 60 vol% of H₂ and CO at 400 °C, GHSV = 10,000 h⁻¹ using a reaction mixture: DMM:O₂:N₂ = 28.6:14.3:57.1 (vol%).

Язык оригинала	английский
Страницы (с-по)	196-202
Число страниц	7
Журнал	Topics in Catalysis
Том	63
Номер выпуска	1-2
DOI	https://doi.org/10.1007/s11244-019-01207-9
Состояние	Опубликовано - 1 мар 2020

Предметные области OECD FOS+WOS

1.04 ХИМИЧЕСКИЕ НАУКИ

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10.1007/s11244-019-01207-9

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title = "Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts",

abstract = "Catalytic partial oxidation (PO) of dimethoxymethane (DMM) to syngas was investigated in a fixed-bed continuous flow reactor under ambient pressure and at 250–500 °C over Pt-, Rh- and Ru-supported on Ce0.75Zr0.25O2–δ catalysts. The Pt catalyst was found to be the most active and selective. It provided complete conversion of DMM to gas mixture containing ˃ 60 vol% of H2 and CO at 400 °C, GHSV = 10,000 h−1 using a reaction mixture: DMM:O2:N2 = 28.6:14.3:57.1 (vol%).",

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Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts. / Badmaev, S. D.; Akhmetov, N. O.; Sobyanin, V. A.

В: Topics in Catalysis, Том 63, № 1-2, 01.03.2020, стр. 196-202.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Partial Oxidation of Dimethoxymethane to Syngas Over Supported Noble Metal Catalysts

AU - Badmaev, S. D.

AU - Akhmetov, N. O.

AU - Sobyanin, V. A.

PY - 2020/3/1

Y1 - 2020/3/1

N2 - Catalytic partial oxidation (PO) of dimethoxymethane (DMM) to syngas was investigated in a fixed-bed continuous flow reactor under ambient pressure and at 250–500 °C over Pt-, Rh- and Ru-supported on Ce0.75Zr0.25O2–δ catalysts. The Pt catalyst was found to be the most active and selective. It provided complete conversion of DMM to gas mixture containing ˃ 60 vol% of H2 and CO at 400 °C, GHSV = 10,000 h−1 using a reaction mixture: DMM:O2:N2 = 28.6:14.3:57.1 (vol%).

AB - Catalytic partial oxidation (PO) of dimethoxymethane (DMM) to syngas was investigated in a fixed-bed continuous flow reactor under ambient pressure and at 250–500 °C over Pt-, Rh- and Ru-supported on Ce0.75Zr0.25O2–δ catalysts. The Pt catalyst was found to be the most active and selective. It provided complete conversion of DMM to gas mixture containing ˃ 60 vol% of H2 and CO at 400 °C, GHSV = 10,000 h−1 using a reaction mixture: DMM:O2:N2 = 28.6:14.3:57.1 (vol%).

KW - Dimethoxymethane

KW - Noble metal catalyst

KW - Partial oxidation

KW - Pt

KW - SOFC

KW - Syngas production

KW - METHANOL

KW - HYDROGEN-RICH GAS

KW - RH

KW - DIMETHYL ETHER

KW - DECOMPOSITION

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U2 - 10.1007/s11244-019-01207-9

DO - 10.1007/s11244-019-01207-9

M3 - Article

AN - SCOPUS:85075375097

VL - 63

SP - 196

EP - 202

JO - Topics in Catalysis

JF - Topics in Catalysis

SN - 1022-5528

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