Аннотация
Metal-free H 2 activations are unusual but interesting for catalytic transformations, particularly in parahydrogen-based nuclear spin hyperpolarization techniques. We demonstrate that metal-free singlet phosphorus biradicaloid, [P(μ-NTer)] 2 , provides pronounced 1 H and 31 P hyperpolarization while activating the parahydrogen molecules. A brief analysis of the resulting NMR signals and the important kinetic parameters are presented.
Язык оригинала | английский |
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Страницы (с-по) | 5890-5893 |
Число страниц | 4 |
Журнал | Physical Chemistry Chemical Physics |
Том | 21 |
Номер выпуска | 11 |
DOI | |
Состояние | Опубликовано - 13 мар. 2019 |