Oxygen release technique: Ba0.5Sr0.5(Co0.8Fe0.2)0.85Ta0.15O3-δ

B. Voloshin; V. A. Eremin; M. P. Popov; A. P. Nemudry

doi:10.1016/j.matpr.2019.12.169

Oxygen release technique: Ba_0.5Sr_0.5(Co_0.8Fe_0.2)_0.85Ta_0.15O_3-_δ

B. Voloshin, V. A. Eremin, M. P. Popov, A. P. Nemudry

Результат исследования: Научные публикации в периодических изданиях › статья по материалам конференции › рецензирование

Аннотация

The work is related to the development of novel oxygen release technique to obtain continuous phase diagrams of oxides with mixed ionic-electronic conductivity. Promising perovskite-like composition Ba_0.5Sr_0.5(Co_0.8Fe_0.2)_0.85Ta_0.15O_3-_δ (BSCFT15) was chosen as a sample. As-prepared samples of BSCFT15 was studied by means of X-Ray diffraction analysis and scanning electron microscopy. Continuous equilibrium phase «3-δ- lg pO₂ - T» diagram obtained by oxygen release technique is presented for the composition BSCFT15 for the first time. The diagrams allowed us to detect the new phase transition P¹ (low temperature phase, Pm-3m) - P² (high-temperature phase, Fm-3c).

Язык оригинала	английский
Страницы (с-по)	455-457
Число страниц	3
Журнал	Materials Today: Proceedings
Том	25
DOI	https://doi.org/10.1016/j.matpr.2019.12.169
Состояние	Опубликовано - 2019
Событие	3rd All-Russian Conference, with International Participation Hot Topics of Solid State Chemistry : From New Ideas to New Materials, HTSSC 2019 - Novosibirsk, Российская Федерация Продолжительность: 1 окт. 2019 → 5 окт. 2019

Доступ к документу

10.1016/j.matpr.2019.12.169

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Ссылка на публикацию в Scopus

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title = "Oxygen release technique: Ba0.5Sr0.5(Co0.8Fe0.2)0.85Ta0.15O3-δ",

abstract = "The work is related to the development of novel oxygen release technique to obtain continuous phase diagrams of oxides with mixed ionic-electronic conductivity. Promising perovskite-like composition Ba0.5Sr0.5(Co0.8Fe0.2)0.85Ta0.15O3-δ (BSCFT15) was chosen as a sample. As-prepared samples of BSCFT15 was studied by means of X-Ray diffraction analysis and scanning electron microscopy. Continuous equilibrium phase «3-δ- lg pO2 - T» diagram obtained by oxygen release technique is presented for the composition BSCFT15 for the first time. The diagrams allowed us to detect the new phase transition P1 (low temperature phase, Pm-3m) - P2 (high-temperature phase, Fm-3c).",

keywords = "BSCF, Continuous phase diagram, Oxygen exchange, Perovskite, Tantalum",

author = "B. Voloshin and Eremin, {V. A.} and Popov, {M. P.} and Nemudry, {A. P.}",

note = "Funding Information: The work was supported by grant of the President of Russian Federation 2019–2020 No. MК-1291.2019.3.; 3rd All-Russian Conference, with International Participation Hot Topics of Solid State Chemistry : From New Ideas to New Materials, HTSSC 2019 ; Conference date: 01-10-2019 Through 05-10-2019",

year = "2019",

doi = "10.1016/j.matpr.2019.12.169",

language = "English",

volume = "25",

pages = "455--457",

journal = "Materials Today: Proceedings",

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publisher = "Elsevier Science B.V.",

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Oxygen release technique : Ba_0.5Sr_0.5(Co_0.8Fe_0.2)_0.85Ta_0.15O_3-_δ. / Voloshin, B.; Eremin, V. A.; Popov, M. P. и др.

В: Materials Today: Proceedings, Том 25, 2019, стр. 455-457.

Результат исследования: Научные публикации в периодических изданиях › статья по материалам конференции › рецензирование

TY - JOUR

T1 - Oxygen release technique

T2 - 3rd All-Russian Conference, with International Participation Hot Topics of Solid State Chemistry : From New Ideas to New Materials, HTSSC 2019

AU - Voloshin, B.

AU - Eremin, V. A.

AU - Popov, M. P.

AU - Nemudry, A. P.

N1 - Funding Information: The work was supported by grant of the President of Russian Federation 2019–2020 No. MК-1291.2019.3.

PY - 2019

Y1 - 2019

N2 - The work is related to the development of novel oxygen release technique to obtain continuous phase diagrams of oxides with mixed ionic-electronic conductivity. Promising perovskite-like composition Ba0.5Sr0.5(Co0.8Fe0.2)0.85Ta0.15O3-δ (BSCFT15) was chosen as a sample. As-prepared samples of BSCFT15 was studied by means of X-Ray diffraction analysis and scanning electron microscopy. Continuous equilibrium phase «3-δ- lg pO2 - T» diagram obtained by oxygen release technique is presented for the composition BSCFT15 for the first time. The diagrams allowed us to detect the new phase transition P1 (low temperature phase, Pm-3m) - P2 (high-temperature phase, Fm-3c).

AB - The work is related to the development of novel oxygen release technique to obtain continuous phase diagrams of oxides with mixed ionic-electronic conductivity. Promising perovskite-like composition Ba0.5Sr0.5(Co0.8Fe0.2)0.85Ta0.15O3-δ (BSCFT15) was chosen as a sample. As-prepared samples of BSCFT15 was studied by means of X-Ray diffraction analysis and scanning electron microscopy. Continuous equilibrium phase «3-δ- lg pO2 - T» diagram obtained by oxygen release technique is presented for the composition BSCFT15 for the first time. The diagrams allowed us to detect the new phase transition P1 (low temperature phase, Pm-3m) - P2 (high-temperature phase, Fm-3c).

KW - BSCF

KW - Continuous phase diagram

KW - Oxygen exchange

KW - Perovskite

KW - Tantalum

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U2 - 10.1016/j.matpr.2019.12.169

DO - 10.1016/j.matpr.2019.12.169

M3 - Conference article

AN - SCOPUS:85086931883

VL - 25

SP - 455

EP - 457

JO - Materials Today: Proceedings

JF - Materials Today: Proceedings

SN - 2214-7853

Y2 - 1 October 2019 through 5 October 2019