Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3–C4 Hydrocarbons

Vladimir I. Sobolev, Konstantin Yu Koltunov, Galina A. Zenkovets

Результат исследования: Научные публикации в периодических изданияхстатья

4 Цитирования (Scopus)

Аннотация

Abstract: The influence of light hydrocarbons, such as n-butane, isobutane, propylene, cis- and trans-2-butenes, and isobutene on the oxidative dehydrogenation of 1-butene to 1,3-butadiene over BiMoKNiCoFePOx/SiO2catalyst has been studied using a gas flow reactor. The inhibition effect of the listed hydrocarbons on the target reaction increased in the order of n-butane ~ isobutane < propylene < 2-butenes < isobutene. In addition, in contrast to 1-butene, isobutene has shown significant contribution to coke formation. It was suggested, that the coke formation and therefore the rate of the catalyst regeneration exercise a significant influence on the efficiency of 1-butene transformation into 1,3-butadiene in the concurrent presence of other hydrocarbons. Graphical Abstract: [Figure not available: see fulltext.]

Язык оригиналаанглийский
Страницы (с-по)310-317
Число страниц8
ЖурналCatalysis Letters
Том147
Номер выпуска2
DOI
СостояниеОпубликовано - фев 2017

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