3 Цитирования (Scopus)


Direct oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(ii) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities.

Язык оригиналаанглийский
Страницы (с-по)15293-15301
Число страниц9
ЖурналNew Journal of Chemistry
Номер выпуска38
СостояниеОпубликовано - 14 окт 2019

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