Аннотация
The review presents the progress in the analysis of low-temperature heat capacity of the metal-organic framework Zn2(C8H4O4)2·C6H12N2 (Zn-DMOF). In Zn-DMOF, left-twisted D3(S) and right-twisted D3(R) DABCO molecules (C6H12N2) can transform into each other by tunneling to form a racemate. Termination of tunneling leads to a phase transition in the subsystem of twisted molecules. It is suggested that Zn-DMOF may be considered a model system to study the mechanisms of phase transitions belonging to the same type as hypothetical Salam phase transitions.
Язык оригинала | английский |
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Номер статьи | 657 |
Число страниц | 9 |
Журнал | Symmetry |
Том | 11 |
Номер выпуска | 5 |
DOI | |
Состояние | Опубликовано - 1 мая 2019 |