Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework

Thien D. Duong; Sergey A. Sapchenko; Ivan Da Silva; Harry G.W. Godfrey; Yongqiang Cheng; Luke L. Daemen; Pascal Manuel; Anibal J. Ramirez-Cuesta; Sihai Yang; Martin Schröder

doi:10.1021/jacs.8b08504

Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework

Thien D. Duong, Sergey A. Sapchenko, Ivan Da Silva, Harry G.W. Godfrey, Yongqiang Cheng, Luke L. Daemen, Pascal Manuel, Anibal J. Ramirez-Cuesta, Sihai Yang, Martin Schröder

Результат исследования: Научные публикации в периодических изданиях › статья

11 Цитирования (Scopus)

Аннотация

We report the first example of crystallographic observation of acetylene binding to -NO₂ groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO₂ groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO₂. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm³ g^-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO₂ groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO₂.

Язык оригинала	английский
Страницы (с-по)	16006-16009
Число страниц	4
Журнал	Journal of the American Chemical Society
Том	140
Номер выпуска	47
DOI	https://doi.org/10.1021/jacs.8b08504
Состояние	Опубликовано - 28 ноя 2018

Доступ к документу

10.1021/jacs.8b08504

Link to publication in Scopus

Fingerprint Подробные сведения о темах исследования «Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

Duong, T. D., Sapchenko, S. A., Da Silva, I., Godfrey, H. G. W., Cheng, Y., Daemen, L. L., Manuel, P., Ramirez-Cuesta, A. J., Yang, S., & Schröder, M. (2018). Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework. Journal of the American Chemical Society, 140(47), 16006-16009. https://doi.org/10.1021/jacs.8b08504

@article{db4f315095df44819e6b9ff1b836c3ad,

title = "Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework",

abstract = "We report the first example of crystallographic observation of acetylene binding to -NO2 groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO2. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm3 g-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO2 groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO2.",

keywords = "ADSORPTION PROPERTIES, C2H2 ADSORPTION, CH4 STORAGE, CO2 ADSORPTION, METHANE, MOFS, SEPARATION, SITES, STORAGE CAPACITY",

author = "Duong, {Thien D.} and Sapchenko, {Sergey A.} and {Da Silva}, Ivan and Godfrey, {Harry G.W.} and Yongqiang Cheng and Daemen, {Luke L.} and Pascal Manuel and Ramirez-Cuesta, {Anibal J.} and Sihai Yang and Martin Schr{\"o}der",

year = "2018",

month = nov,

day = "28",

doi = "10.1021/jacs.8b08504",

language = "English",

volume = "140",

pages = "16006--16009",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "47",

}

Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework. / Duong, Thien D.; Sapchenko, Sergey A.; Da Silva, Ivan; Godfrey, Harry G.W.; Cheng, Yongqiang; Daemen, Luke L.; Manuel, Pascal; Ramirez-Cuesta, Anibal J.; Yang, Sihai; Schröder, Martin.

В: Journal of the American Chemical Society, Том 140, № 47, 28.11.2018, стр. 16006-16009.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework

AU - Duong, Thien D.

AU - Sapchenko, Sergey A.

AU - Da Silva, Ivan

AU - Godfrey, Harry G.W.

AU - Cheng, Yongqiang

AU - Daemen, Luke L.

AU - Manuel, Pascal

AU - Ramirez-Cuesta, Anibal J.

AU - Yang, Sihai

AU - Schröder, Martin

PY - 2018/11/28

Y1 - 2018/11/28

N2 - We report the first example of crystallographic observation of acetylene binding to -NO2 groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO2. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm3 g-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO2 groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO2.

AB - We report the first example of crystallographic observation of acetylene binding to -NO2 groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO2. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm3 g-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO2 groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO2.

KW - ADSORPTION PROPERTIES

KW - C2H2 ADSORPTION

KW - CH4 STORAGE

KW - CO2 ADSORPTION

KW - METHANE

KW - MOFS

KW - SEPARATION

KW - SITES

KW - STORAGE CAPACITY

UR - http://www.scopus.com/inward/record.url?scp=85056789220&partnerID=8YFLogxK

U2 - 10.1021/jacs.8b08504

DO - 10.1021/jacs.8b08504

M3 - Article

C2 - 30285424

AN - SCOPUS:85056789220

VL - 140

SP - 16006

EP - 16009

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 47

ER -