Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework

Thien D. Duong; Sergey A. Sapchenko; Ivan Da Silva; Harry G.W. Godfrey; Yongqiang Cheng; Luke L. Daemen; Pascal Manuel; Anibal J. Ramirez-Cuesta; Sihai Yang; Martin Schröder

doi:10.1021/jacs.8b08504

Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework

Thien D. Duong, Sergey A. Sapchenko, Ivan Da Silva, Harry G.W. Godfrey, Yongqiang Cheng, Luke L. Daemen, Pascal Manuel, Anibal J. Ramirez-Cuesta, Sihai Yang, Martin Schröder

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

15 Цитирования (Scopus)

Аннотация

We report the first example of crystallographic observation of acetylene binding to -NO₂ groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO₂ groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO₂. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm³ g^-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO₂ groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO₂.

Язык оригинала	английский
Страницы (с-по)	16006-16009
Число страниц	4
Журнал	Journal of the American Chemical Society
Том	140
Номер выпуска	47
DOI	https://doi.org/10.1021/jacs.8b08504
Состояние	Опубликовано - 28 ноя 2018

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10.1021/jacs.8b08504

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title = "Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework",

abstract = "We report the first example of crystallographic observation of acetylene binding to -NO2 groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO2. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm3 g-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO2 groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO2.",

keywords = "ADSORPTION PROPERTIES, C2H2 ADSORPTION, CH4 STORAGE, CO2 ADSORPTION, METHANE, MOFS, SEPARATION, SITES, STORAGE CAPACITY",

author = "Duong, {Thien D.} and Sapchenko, {Sergey A.} and {Da Silva}, Ivan and Godfrey, {Harry G.W.} and Yongqiang Cheng and Daemen, {Luke L.} and Pascal Manuel and Ramirez-Cuesta, {Anibal J.} and Sihai Yang and Martin Schr{\"o}der",

year = "2018",

month = nov,

day = "28",

doi = "10.1021/jacs.8b08504",

language = "English",

volume = "140",

pages = "16006--16009",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework. / Duong, Thien D.; Sapchenko, Sergey A.; Da Silva, Ivan; Godfrey, Harry G.W.; Cheng, Yongqiang; Daemen, Luke L.; Manuel, Pascal; Ramirez-Cuesta, Anibal J.; Yang, Sihai; Schröder, Martin.

В: Journal of the American Chemical Society, Том 140, № 47, 28.11.2018, стр. 16006-16009.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework

AU - Duong, Thien D.

AU - Sapchenko, Sergey A.

AU - Da Silva, Ivan

AU - Godfrey, Harry G.W.

AU - Cheng, Yongqiang

AU - Daemen, Luke L.

AU - Manuel, Pascal

AU - Ramirez-Cuesta, Anibal J.

AU - Yang, Sihai

AU - Schröder, Martin

PY - 2018/11/28

Y1 - 2018/11/28

N2 - We report the first example of crystallographic observation of acetylene binding to -NO2 groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO2. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm3 g-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO2 groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO2.

AB - We report the first example of crystallographic observation of acetylene binding to -NO2 groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO2. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm3 g-1 at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scattering experiments reveal the role of -NO2 groups, in cooperation with open metal sites, in the binding of acetylene in MFM-102-NO2.

KW - ADSORPTION PROPERTIES

KW - C2H2 ADSORPTION

KW - CH4 STORAGE

KW - CO2 ADSORPTION

KW - METHANE

KW - MOFS

KW - SEPARATION

KW - SITES

KW - STORAGE CAPACITY

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U2 - 10.1021/jacs.8b08504

DO - 10.1021/jacs.8b08504

M3 - Article

C2 - 30285424

AN - SCOPUS:85056789220

VL - 140

SP - 16006

EP - 16009

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 47

ER -

Optimal Binding of Acetylene to a Nitro-Decorated Metal-Organic Framework

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