One-pot synthesis of (Mo6I8)4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction

Natalya A. Vorotnikova, Mariya V. Edeleva, Olga G. Kurskaya, Konstantin A. Brylev, Alexander M. Shestopalov, Yuri V. Mironov, Andrew J. Sutherland, Olga A. Efremova, Michael A. Shestopalov

Результат исследования: Научные публикации в периодических изданияхстатья

7 Цитирования (Scopus)

Аннотация

Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [(Mo6X8)(NO3)6]2- (X=Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated.

Язык оригиналаанглийский
Страницы (с-по)1906-1912
Число страниц7
ЖурналPolymer International
Том66
Номер выпуска12
DOI
СостояниеОпубликовано - 1 дек 2017

Fingerprint Подробные сведения о темах исследования «One-pot synthesis of (Mo<sub>6</sub>I<sub>8</sub>)<sup>4+</sup>-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction». Вместе они формируют уникальный семантический отпечаток (fingerprint).

  • Цитировать