@article{f8e74d4eedc94910ad6ec5713544a5f0,
title = "One-Dimensional Diiodine-Iodobismuthate(III) Hybrids Cat3{[Bi2I9](I2)3}: Syntheses, Stability, and Optical Properties",
abstract = "One-dimensional iodine-rich iodobismuthates(III), Cat3{[Bi2I9](I2)3} [Cat = 1,4-MePy (1) and 1-EtBMAP (2)], feature the highest amount of {"}trapped{"}diiodine units in polyhalogen-halometalates of p-block elements. Both complexes have narrow optical band gaps (1.55 and 1.63 eV, respectively) and moderate thermal stability.",
author = "Usoltsev, {Andrey N.} and Korobeynikov, {Nikita A.} and Novikov, {Alexander S.} and Plyusnin, {Pavel E.} and Kolesov, {Boris A.} and Fedin, {Vladimir P.} and Sokolov, {Maxim N.} and Adonin, {Sergey A.}",
note = "Funding Information: This work was supported by the Russian Science Foundation (Grant 18-73-10040). The authors thank Dr. Ilya V. Korolkov (NIIC SB RAS) for assistance with PXRD measurements. Publisher Copyright: {\textcopyright} 2020 American Chemical Society. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = dec,
day = "7",
doi = "10.1021/acs.inorgchem.0c02599",
language = "English",
volume = "59",
pages = "17320--17325",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "23",
}