Octahedral chalcogenide rhenium cluster complexes with imidazole

Dmitry I. Konovalov; Anton A. Ivanov; Yuri A. Vorotnikov; Anton I. Smolentsev; Ilia V. Eltsov; Olga A. Efremova; Noboru Kitamura; Yuri V. Mironov; Michael A. Shestopalov

doi:10.1016/j.poly.2019.03.007

Octahedral chalcogenide rhenium cluster complexes with imidazole

Dmitry I. Konovalov, Anton A. Ivanov, Yuri A. Vorotnikov, Anton I. Smolentsev, Ilia V. Eltsov, Olga A. Efremova, Noboru Kitamura, Yuri V. Mironov, Michael A. Shestopalov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

7 Цитирования (Scopus)

Аннотация

Reactions of [{Re ₆ Q ₈ }Br ₆ ] ^4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re ₆ Q ₈ }(imzH) ₄ (imz) ₂ ] (imzH = imidazole). The interaction of [{Re ₆ Q ₈ }(imzH) ₄ (imz) ₂ ] with hydrohalic acids resulted in cationic complexes [{Re ₆ Q ₈ }(imzH) ₆ ]X ₂ (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re ₆ Q ₈ }(imzH) ₄ (imz) ₂ ] was also studied.

Язык оригинала	английский
Страницы (с-по)	79-85
Число страниц	7
Журнал	Polyhedron
Том	165
DOI	https://doi.org/10.1016/j.poly.2019.03.007
Состояние	Опубликовано - 1 июн 2019

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10.1016/j.poly.2019.03.007

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@article{1595fa4e159d4f2abaab2b0ff85d35a4,

title = "Octahedral chalcogenide rhenium cluster complexes with imidazole",

abstract = " Reactions of [{Re 6 Q 8 }Br 6 ] 4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] (imzH = imidazole). The interaction of [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] with hydrohalic acids resulted in cationic complexes [{Re 6 Q 8 }(imzH) 6 ]X 2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] was also studied. ",

keywords = "Crystal structure, Imidazole, Luminescence, Protonation, Rhenium cluster, RETENTION, PYRIDINE, CL, SE, LUMINESCENCE, LIGANDS, HEXARHENIUM(III) COMPLEXES, REDOX, METAL, EMISSION",

author = "Konovalov, {Dmitry I.} and Ivanov, {Anton A.} and Vorotnikov, {Yuri A.} and Smolentsev, {Anton I.} and Eltsov, {Ilia V.} and Efremova, {Olga A.} and Noboru Kitamura and Mironov, {Yuri V.} and Shestopalov, {Michael A.}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2019",

month = jun,

day = "1",

doi = "10.1016/j.poly.2019.03.007",

language = "English",

volume = "165",

pages = "79--85",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

}

Octahedral chalcogenide rhenium cluster complexes with imidazole. / Konovalov, Dmitry I.; Ivanov, Anton A.; Vorotnikov, Yuri A.; Smolentsev, Anton I.; Eltsov, Ilia V.; Efremova, Olga A.; Kitamura, Noboru; Mironov, Yuri V.; Shestopalov, Michael A.

В: Polyhedron, Том 165, 01.06.2019, стр. 79-85.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Octahedral chalcogenide rhenium cluster complexes with imidazole

AU - Konovalov, Dmitry I.

AU - Ivanov, Anton A.

AU - Vorotnikov, Yuri A.

AU - Smolentsev, Anton I.

AU - Eltsov, Ilia V.

AU - Efremova, Olga A.

AU - Kitamura, Noboru

AU - Mironov, Yuri V.

AU - Shestopalov, Michael A.

PY - 2019/6/1

Y1 - 2019/6/1

N2 - 6 Q 8 }Br 6 ] 4−/3− 6 Q 8 }(imzH) 4 (imz) 2 6 Q 8 }(imzH) 4 (imz) 2 6 Q 8 }(imzH) 6 ]X 2 6 Q 8 }(imzH) 4 (imz) 2 Reactions of [{Re (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re ] (imzH = imidazole). The interaction of [{Re ] with hydrohalic acids resulted in cationic complexes [{Re (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re ] was also studied.

AB - Reactions of [{Re 6 Q 8 }Br 6 ] 4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] (imzH = imidazole). The interaction of [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] with hydrohalic acids resulted in cationic complexes [{Re 6 Q 8 }(imzH) 6 ]X 2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re 6 Q 8 }(imzH) 4 (imz) 2 ] was also studied.

KW - Crystal structure

KW - Imidazole

KW - Luminescence

KW - Protonation

KW - Rhenium cluster

KW - RETENTION

KW - PYRIDINE

KW - CL

KW - SE

KW - LUMINESCENCE

KW - LIGANDS

KW - HEXARHENIUM(III) COMPLEXES

KW - REDOX

KW - METAL

KW - EMISSION

UR - http://www.scopus.com/inward/record.url?scp=85063519918&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2019.03.007

DO - 10.1016/j.poly.2019.03.007

M3 - Article

AN - SCOPUS:85063519918

VL - 165

SP - 79

EP - 85

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

Octahedral chalcogenide rhenium cluster complexes with imidazole

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