Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand

P. A. Petrov; M. Yu Afonin; D. Yu Naumov; S. N. Konchenko; A. V. Piskunov

doi:10.1134/S1070328415010078

Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand

P. A. Petrov, M. Yu Afonin, D. Yu Naumov, S. N. Konchenko, A. V. Piskunov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

4 Цитирования (Scopus)

Аннотация

A reaction of the cluster (Et₄N)₂[Mo₃S₇Br₆] with potassium 3,6-di-tert-butyl-o-benzosemiquinolate (KSQ³⁶) afforded the mononuclear complexes (Et₄N)[Mo(Cat³⁶)₃] (I) and (Et₄N)[MoO(Cat³⁶)₂(HCat³⁶)] (II) with prismatic and octahedral environments of their central metal atoms, respectively. Complex I was also obtained by a reaction between MoCl₅, sodium 3,6-di-tert-butylcatecholate (Na₂Cat³⁶), and Et₄NBr. Complexes I and II were characterized by X-ray diffraction and EPR spectroscopy. The structures have been deposited with the Cambridge Structural Database (nos. 1009139 (I), 1009140 (I · 1.5THF), and 1009141 (II · Et₂O)).

Язык оригинала	английский
Страницы (с-по)	31-36
Число страниц	6
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	41
Номер выпуска	1
DOI	https://doi.org/10.1134/S1070328415010078
Состояние	Опубликовано - 1 янв. 2015

Доступ к документу

10.1134/S1070328415010078

Другие файлы и ссылки

Link to publication in Scopus

Цитировать

@article{4335744abbb1449baabcfcfe54d7641b,

title = "Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand",

abstract = "A reaction of the cluster (Et4N)2[Mo3S7Br6] with potassium 3,6-di-tert-butyl-o-benzosemiquinolate (KSQ36) afforded the mononuclear complexes (Et4N)[Mo(Cat36)3] (I) and (Et4N)[MoO(Cat36)2(HCat36)] (II) with prismatic and octahedral environments of their central metal atoms, respectively. Complex I was also obtained by a reaction between MoCl5, sodium 3,6-di-tert-butylcatecholate (Na2Cat36), and Et4NBr. Complexes I and II were characterized by X-ray diffraction and EPR spectroscopy. The structures have been deposited with the Cambridge Structural Database (nos. 1009139 (I), 1009140 (I · 1.5THF), and 1009141 (II · Et2O)).",

author = "Petrov, {P. A.} and Afonin, {M. Yu} and Naumov, {D. Yu} and Konchenko, {S. N.} and Piskunov, {A. V.}",

year = "2015",

month = jan,

day = "1",

doi = "10.1134/S1070328415010078",

language = "English",

volume = "41",

pages = "31--36",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "1",

}

Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand. / Petrov, P. A.; Afonin, M. Yu; Naumov, D. Yu и др.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 41, № 1, 01.01.2015, стр. 31-36.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand

AU - Petrov, P. A.

AU - Afonin, M. Yu

AU - Naumov, D. Yu

AU - Konchenko, S. N.

AU - Piskunov, A. V.

PY - 2015/1/1

Y1 - 2015/1/1

N2 - A reaction of the cluster (Et4N)2[Mo3S7Br6] with potassium 3,6-di-tert-butyl-o-benzosemiquinolate (KSQ36) afforded the mononuclear complexes (Et4N)[Mo(Cat36)3] (I) and (Et4N)[MoO(Cat36)2(HCat36)] (II) with prismatic and octahedral environments of their central metal atoms, respectively. Complex I was also obtained by a reaction between MoCl5, sodium 3,6-di-tert-butylcatecholate (Na2Cat36), and Et4NBr. Complexes I and II were characterized by X-ray diffraction and EPR spectroscopy. The structures have been deposited with the Cambridge Structural Database (nos. 1009139 (I), 1009140 (I · 1.5THF), and 1009141 (II · Et2O)).

AB - A reaction of the cluster (Et4N)2[Mo3S7Br6] with potassium 3,6-di-tert-butyl-o-benzosemiquinolate (KSQ36) afforded the mononuclear complexes (Et4N)[Mo(Cat36)3] (I) and (Et4N)[MoO(Cat36)2(HCat36)] (II) with prismatic and octahedral environments of their central metal atoms, respectively. Complex I was also obtained by a reaction between MoCl5, sodium 3,6-di-tert-butylcatecholate (Na2Cat36), and Et4NBr. Complexes I and II were characterized by X-ray diffraction and EPR spectroscopy. The structures have been deposited with the Cambridge Structural Database (nos. 1009139 (I), 1009140 (I · 1.5THF), and 1009141 (II · Et2O)).

UR - http://www.scopus.com/inward/record.url?scp=84936997047&partnerID=8YFLogxK

U2 - 10.1134/S1070328415010078

DO - 10.1134/S1070328415010078

M3 - Article

AN - SCOPUS:84936997047

VL - 41

SP - 31

EP - 36

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 1

ER -

Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand

Аннотация

Доступ к документу

Другие файлы и ссылки

Fingerprint

Цитировать