Nonoxidative Conversion of Methane to Aromatic Hydrocarbons in the Presence of ZSM-5 Zeolites Modified with Molybdenum and Rhenium

A. A. Stepanov, V. I. Zaikovskii, L. L. Korobitsyna, A. V. Vosmerikov

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

The nonoxidative conversion of methane to aromatic hydrocarbons in the presence of a high-silica ZSM-5 zeolite modified with molybdenum and rhenium nanopowders has been studied. Data on the acid characteristics of the catalysts have been derived by temperature-programmed desorption of ammonia. The microstructure and composition of the Re/ZSM-5 and Re–Mo/ZSM-5 catalyst systems have been studied by transmission electron microscopy. It has been shown that modification of a Mo-containing zeolite with rhenium leads to an increase in the activity and stability of the catalyst in the methane dehydroaromatization reaction.

Язык оригиналаанглийский
Страницы (с-по)91-98
Число страниц8
ЖурналPetroleum Chemistry
Том59
Номер выпуска1
DOI
СостояниеОпубликовано - 1 янв 2019

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