Noncentrosymmetric Na2Ca4(CO3)5 Carbonate of "m13M23XY3Z" Structural Type and Affinity between Borate and Carbonate Structures for Design of New Optical Materials

Sergey V. Rashchenko; Vladimir V. Bakakin; Anton F. Shatskiy; Pavel N. Gavryushkin; Yurii V. Seryotkin; Konstantin D. Litasov

doi:10.1021/acs.cgd.7b01161

Noncentrosymmetric Na₂Ca₄(CO₃)₅ Carbonate of "m1₃M2₃XY₃Z" Structural Type and Affinity between Borate and Carbonate Structures for Design of New Optical Materials

Sergey V. Rashchenko, Vladimir V. Bakakin, Anton F. Shatskiy, Pavel N. Gavryushkin, Yurii V. Seryotkin, Konstantin D. Litasov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

9 Цитирования (Scopus)

Аннотация

A number of carbonates with promising optical properties were synthesized during the past decade, proving the potential of carbonate systems as a source of novel optical materials. Here we report a new noncentrosymmetric Na₂Ca₄(CO₃)₅ carbonate (P6₃mc; a = 10.37402(14) Å, c = 6.25935(9) Å) with "M1₃M2₃XY₃Z" structural type. This structural type, built upon an M1₃M2₃ cationic array with three types of anion-filled voids (X, Y, and Z), can accommodate a variety of cations (alkali, alkaline earth, and rare earth) and anions (carbonate, borate, and halide), as we show by extensive analysis of structures of known compounds, and appears to be very promising for the search of new optical materials.

Язык оригинала	английский
Страницы (с-по)	6079-6084
Число страниц	6
Журнал	Crystal Growth and Design
Том	17
Номер выпуска	11
DOI	https://doi.org/10.1021/acs.cgd.7b01161
Состояние	Опубликовано - 1 ноя 2017

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10.1021/acs.cgd.7b01161

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Rashchenko, Sergey V. ; Bakakin, Vladimir V. ; Shatskiy, Anton F. ; Gavryushkin, Pavel N. ; Seryotkin, Yurii V. ; Litasov, Konstantin D. / Noncentrosymmetric Na₂Ca₄(CO₃)₅ Carbonate of "m1₃M2₃XY₃Z" Structural Type and Affinity between Borate and Carbonate Structures for Design of New Optical Materials. В: Crystal Growth and Design. 2017 ; Том 17, № 11. стр. 6079-6084.

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title = "Noncentrosymmetric Na2Ca4(CO3)5 Carbonate of {"}m13M23XY3Z{"} Structural Type and Affinity between Borate and Carbonate Structures for Design of New Optical Materials",

abstract = "A number of carbonates with promising optical properties were synthesized during the past decade, proving the potential of carbonate systems as a source of novel optical materials. Here we report a new noncentrosymmetric Na2Ca4(CO3)5 carbonate (P63mc; a = 10.37402(14) {\AA}, c = 6.25935(9) {\AA}) with {"}M13M23XY3Z{"} structural type. This structural type, built upon an M13M23 cationic array with three types of anion-filled voids (X, Y, and Z), can accommodate a variety of cations (alkali, alkaline earth, and rare earth) and anions (carbonate, borate, and halide), as we show by extensive analysis of structures of known compounds, and appears to be very promising for the search of new optical materials.",

keywords = "SINGLE-CRYSTAL DATA, FLUORIDE CARBONATE, NYEREREITE, HALIDES, SYSTEM, STATE, SR, BA, CA",

author = "Rashchenko, {Sergey V.} and Bakakin, {Vladimir V.} and Shatskiy, {Anton F.} and Gavryushkin, {Pavel N.} and Seryotkin, {Yurii V.} and Litasov, {Konstantin D.}",

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doi = "10.1021/acs.cgd.7b01161",

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publisher = "American Chemical Society",

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Noncentrosymmetric Na₂Ca₄(CO₃)₅ Carbonate of "m1₃M2₃XY₃Z" Structural Type and Affinity between Borate and Carbonate Structures for Design of New Optical Materials. / Rashchenko, Sergey V.; Bakakin, Vladimir V.; Shatskiy, Anton F.; Gavryushkin, Pavel N.; Seryotkin, Yurii V.; Litasov, Konstantin D.

В: Crystal Growth and Design, Том 17, № 11, 01.11.2017, стр. 6079-6084.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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T1 - Noncentrosymmetric Na2Ca4(CO3)5 Carbonate of "m13M23XY3Z" Structural Type and Affinity between Borate and Carbonate Structures for Design of New Optical Materials

AU - Rashchenko, Sergey V.

AU - Bakakin, Vladimir V.

AU - Shatskiy, Anton F.

AU - Gavryushkin, Pavel N.

AU - Seryotkin, Yurii V.

AU - Litasov, Konstantin D.

PY - 2017/11/1

Y1 - 2017/11/1

N2 - A number of carbonates with promising optical properties were synthesized during the past decade, proving the potential of carbonate systems as a source of novel optical materials. Here we report a new noncentrosymmetric Na2Ca4(CO3)5 carbonate (P63mc; a = 10.37402(14) Å, c = 6.25935(9) Å) with "M13M23XY3Z" structural type. This structural type, built upon an M13M23 cationic array with three types of anion-filled voids (X, Y, and Z), can accommodate a variety of cations (alkali, alkaline earth, and rare earth) and anions (carbonate, borate, and halide), as we show by extensive analysis of structures of known compounds, and appears to be very promising for the search of new optical materials.

AB - A number of carbonates with promising optical properties were synthesized during the past decade, proving the potential of carbonate systems as a source of novel optical materials. Here we report a new noncentrosymmetric Na2Ca4(CO3)5 carbonate (P63mc; a = 10.37402(14) Å, c = 6.25935(9) Å) with "M13M23XY3Z" structural type. This structural type, built upon an M13M23 cationic array with three types of anion-filled voids (X, Y, and Z), can accommodate a variety of cations (alkali, alkaline earth, and rare earth) and anions (carbonate, borate, and halide), as we show by extensive analysis of structures of known compounds, and appears to be very promising for the search of new optical materials.

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