Non-isothermal kinetics of spin crossover

Mark B. Bushuev; Elena B. Nikolaenkova; Viktor P. Krivopalov

doi:10.1039/c7cp03442c

Non-isothermal kinetics of spin crossover

Mark B. Bushuev, Elena B. Nikolaenkova, Viktor P. Krivopalov

Кафедра аналитической химии ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья

6 Цитирования (Scopus)

Аннотация

Non-isothermal magnetic studies can be used to estimate the activation energy of cooperative spin transition. Model-free isoconversional integral methods give reliable estimates of the activation barrier height for highly cooperative spin crossover systems with wide thermal hysteresis.

Язык оригинала	английский
Страницы (с-по)	16955-16959
Число страниц	5
Журнал	Physical Chemistry Chemical Physics
Том	19
Номер выпуска	26
DOI	https://doi.org/10.1039/c7cp03442c
Состояние	Опубликовано - 14 июл 2017

Доступ к документу

10.1039/c7cp03442c

Link to publication in Scopus

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abstract = "Non-isothermal magnetic studies can be used to estimate the activation energy of cooperative spin transition. Model-free isoconversional integral methods give reliable estimates of the activation barrier height for highly cooperative spin crossover systems with wide thermal hysteresis.",

keywords = "LARGE THERMAL HYSTERESIS, IRON(II) COMPLEXES, ACTIVATION-ENERGY, TRANSITION, STATE, INTERPLAY, TEMPERATURE, LIGANDS",

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KW - STATE

KW - INTERPLAY

KW - TEMPERATURE

KW - LIGANDS

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