Non-Faraday rotation of the free induction decay of hydroxyl radical in terahertz region

E. N. Chesnokov, V. V. Kubarev, L. N. Krasnoperov, P. V. Koshlyakov

Результат исследования: Публикации в книгах, отчётах, сборниках, трудах конференцийстатья в сборнике материалов конференциинаучнаярецензирование

1 Цитирования (Scopus)

Аннотация

Effect of external longitudinal magnetic field on the optical Free Induction Decay (FID) from a free radical was observed for the first time. The experiments were performed on the rotational transition of hydroxyl radical OH (233/2(J=1) Å 233/2(J=0) at 83.8 cmí1) using the Terahertz Free Electron Laser. In contrast to the results of the experiments with a stable paramagnetic molecule NO, the observed effect of external magnetic field on the Free Induction Decay from hydroxyl radicals is more complicated. A longitudinal magnetic field leads to rotation of the polarization plane of the FID radiation, as well as to additional modulation of the signal intensity. The angle of rotation of the polarization plane is large, in agreement with the theoretical predictions. The observed FID kinetics in the time domain are in semi-quantitative agreement with the modeling. This observation opens an opportunity for selective detection by polarization discrimination of weak signals of short-lived reactive paramagnetic free radicals from overwhelming signals that originate from stable non-paramagnetic species.

Язык оригиналаанглийский
Название основной публикацииSynchrotron and Free Electron Laser Radiation
Подзаголовок основной публикацииGeneration and Application, SFR 2020
РедакторыBoris Knyazev, Nikolay Vinokurov
ИздательAmerican Institute of Physics Inc.
ISBN (электронное издание)9780735440333
DOI
СостояниеОпубликовано - 17 ноя 2020
Событие2020 Internetional Conference on Synchrotron and Free Electron Laser Radiation: Generation and Application, SFR 2020 - Novosibirsk, Российская Федерация
Продолжительность: 13 июл 202016 июл 2020

Серия публикаций

НазваниеAIP Conference Proceedings
Том2299
ISSN (печатное издание)0094-243X
ISSN (электронное издание)1551-7616

Конференция

Конференция2020 Internetional Conference on Synchrotron and Free Electron Laser Radiation: Generation and Application, SFR 2020
СтранаРоссийская Федерация
ГородNovosibirsk
Период13.07.202016.07.2020

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