Nitrous oxide as a selective oxidant for ketonization of C=C double bonds in organic compounds

Konstantin A. Dubkov, Gennadii I. Panov, Valentin N. Parmon

Результат исследования: Научные публикации в периодических изданияхобзорная статья

7 Цитирования (Scopus)

Аннотация

The oxidation chemistry of nitrous oxide (N2O) includes a wide range of both catalytic and non-catalytic selective oxidation reactions. This review summarizes the results of modern experimental and theoretical studies devoted to non-catalytic oxidation reactions ofN2Owith carbon ± carbon double bonds of alkenes and polymers. It is shown that these reactions open up a promising way for the synthesis of diverse carbonyl compounds (ketones and aldehydes) as well as a new type of functionalized oligomersDunsaturated polyketones. Possible applications of unsaturated polyketones, as well as economic aspects of N2O production and use as a selective oxidant are discussed.

Язык оригиналаанглийский
Страницы (с-по)510-529
Число страниц20
ЖурналRussian Chemical Reviews
Том86
Номер выпуска6
DOI
СостояниеОпубликовано - 1 янв 2017

Fingerprint Подробные сведения о темах исследования «Nitrous oxide as a selective oxidant for ketonization of C=C double bonds in organic compounds». Вместе они формируют уникальный семантический отпечаток (fingerprint).

  • Цитировать