[NiEn3]CrO4: Structure, thermal properties, and pseudomorphism

S. P. Khranenko; V. Yu Komarov; E. Yu Gerasimov; A. V. Zadesenets; E. A. Maksimovsky; S. A. Gromilov

doi:10.1134/S0022476617070265

[NiEn₃]CrO₄: Structure, thermal properties, and pseudomorphism

S. P. Khranenko, V. Yu Komarov, E. Yu Gerasimov, A. V. Zadesenets, E. A. Maksimovsky, S. A. Gromilov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

The crystal structure of [NiEn₃]CrO₄ (En is ethylendiamine), C₆H₂₄CrN₆NiO₄ is studied: a = 9.0408(5) Å, c = 9.7466(4) Å, V = 689.92(8) Å³, space group P6₃/mmc, Z = 2, d_x = 1.704 g/cm³, Ni–N 2.133(9) Å, ∠N–Ni–N 82.4(5)°. The thermal properties are determined. When it is heated in a hydrogen atmosphere, a mixture of nanocrystalline Ni and Cr₂O₃ powders with coherent scattering regions of 59 nm and 90 nm respectively is formed. It is demonstrated that thermal decomposition products consist of pseudomorphic particles that inherit the sizes and shapes of initial [NiEn₃]CrO₄ single crystals.

Язык оригинала	английский
Страницы (с-по)	1448-1452
Число страниц	5
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	7
DOI	https://doi.org/10.1134/S0022476617070265
Состояние	Опубликовано - 1 дек 2017

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10.1134/S0022476617070265

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@article{83b30fa69d78496194e30f8e961aee43,

title = "[NiEn3]CrO4: Structure, thermal properties, and pseudomorphism",

abstract = "The crystal structure of [NiEn3]CrO4 (En is ethylendiamine), C6H24CrN6NiO4 is studied: a = 9.0408(5) {\AA}, c = 9.7466(4) {\AA}, V = 689.92(8) {\AA}3, space group P63/mmc, Z = 2, dx = 1.704 g/cm3, Ni–N 2.133(9) {\AA}, ∠N–Ni–N 82.4(5)°. The thermal properties are determined. When it is heated in a hydrogen atmosphere, a mixture of nanocrystalline Ni and Cr2O3 powders with coherent scattering regions of 59 nm and 90 nm respectively is formed. It is demonstrated that thermal decomposition products consist of pseudomorphic particles that inherit the sizes and shapes of initial [NiEn3]CrO4 single crystals.",

keywords = "chromate anion, complex salt, crystal chemistry, ethylendiamine nickel, pseudomorphism, single crystal X-ray diffraction analysis, thermal properties, CRYSTAL-STRUCTURES",

author = "Khranenko, {S. P.} and Komarov, {V. Yu} and Gerasimov, {E. Yu} and Zadesenets, {A. V.} and Maksimovsky, {E. A.} and Gromilov, {S. A.}",

year = "2017",

month = dec,

day = "1",

doi = "10.1134/S0022476617070265",

language = "English",

volume = "58",

pages = "1448--1452",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "7",

}

[NiEn₃]CrO₄ : Structure, thermal properties, and pseudomorphism. / Khranenko, S. P.; Komarov, V. Yu; Gerasimov, E. Yu; Zadesenets, A. V.; Maksimovsky, E. A.; Gromilov, S. A.

В: Journal of Structural Chemistry, Том 58, № 7, 01.12.2017, стр. 1448-1452.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - [NiEn3]CrO4

T2 - Structure, thermal properties, and pseudomorphism

AU - Khranenko, S. P.

AU - Komarov, V. Yu

AU - Gerasimov, E. Yu

AU - Zadesenets, A. V.

AU - Maksimovsky, E. A.

AU - Gromilov, S. A.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - The crystal structure of [NiEn3]CrO4 (En is ethylendiamine), C6H24CrN6NiO4 is studied: a = 9.0408(5) Å, c = 9.7466(4) Å, V = 689.92(8) Å3, space group P63/mmc, Z = 2, dx = 1.704 g/cm3, Ni–N 2.133(9) Å, ∠N–Ni–N 82.4(5)°. The thermal properties are determined. When it is heated in a hydrogen atmosphere, a mixture of nanocrystalline Ni and Cr2O3 powders with coherent scattering regions of 59 nm and 90 nm respectively is formed. It is demonstrated that thermal decomposition products consist of pseudomorphic particles that inherit the sizes and shapes of initial [NiEn3]CrO4 single crystals.

AB - The crystal structure of [NiEn3]CrO4 (En is ethylendiamine), C6H24CrN6NiO4 is studied: a = 9.0408(5) Å, c = 9.7466(4) Å, V = 689.92(8) Å3, space group P63/mmc, Z = 2, dx = 1.704 g/cm3, Ni–N 2.133(9) Å, ∠N–Ni–N 82.4(5)°. The thermal properties are determined. When it is heated in a hydrogen atmosphere, a mixture of nanocrystalline Ni and Cr2O3 powders with coherent scattering regions of 59 nm and 90 nm respectively is formed. It is demonstrated that thermal decomposition products consist of pseudomorphic particles that inherit the sizes and shapes of initial [NiEn3]CrO4 single crystals.

KW - chromate anion

KW - complex salt

KW - crystal chemistry

KW - ethylendiamine nickel

KW - pseudomorphism

KW - single crystal X-ray diffraction analysis

KW - thermal properties

KW - CRYSTAL-STRUCTURES

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U2 - 10.1134/S0022476617070265

DO - 10.1134/S0022476617070265

M3 - Article

AN - SCOPUS:85039861252

VL - 58

SP - 1448

EP - 1452

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

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ER -