Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming

Vladislav A. Sadykov; Mikhail N. Simonov; Natalia V. Mezentseva; Svetlana N. Pavlova; Yulia E. Fedorova; Aleksei S. Bobin; Yulia N. Bespalko; Arcady V. Ishchenko; Tamara A. Krieger; Tatiana S. Glazneva; Tatyana V. Larina; Svetlana V. Cherepanova; Vasilii V. Kaichev; Andrey A. Saraev; Yurii A. Chesalov; Aleksandr N. Shmakov; Anne Cecile Roger; Andrzej Adamski

doi:10.1515/chem-2016-0039

Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH₄ dry reforming

Vladislav A. Sadykov, Mikhail N. Simonov, Natalia V. Mezentseva, Svetlana N. Pavlova, Yulia E. Fedorova, Aleksei S. Bobin, Yulia N. Bespalko, Arcady V. Ishchenko, Tamara A. Krieger, Tatiana S. Glazneva, Tatyana V. Larina, Svetlana V. Cherepanova, Vasilii V. Kaichev, Andrey A. Saraev, Yurii A. Chesalov, Aleksandr N. Shmakov, Anne Cecile Roger, Andrzej Adamski

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

17 Цитирования (Scopus)

Аннотация

Mixed nanocrystalline Ce-Zr-O oxides (Ce/Zr = 1 or 7/3) were prepared by modified Pechini route using ethylene glycol solutions of metal salts. Detailed characterization of their real structure and surface properties by X-ray diffraction on synchrotron radiation with the full-profile Rietveld analysis, high resolution electron microscopy with elemental analysis, Raman spectroscopy, UV-Vis and X-ray photoelectron spectroscopy revealed a high homogeneity of cations distribution in nanodomains resulting in stabilization of disordered cubic phase. This provides a high dispersion of NiO loaded on these mixed oxides by wet impregnation, a high reactivity and mobility of oxygen in these catalysts and strong interaction of Ni with support in the reduced state. This helps to achieve a high activity and coking stability of developed catalysts in CH₄ dry reforming in feeds with CH₄ concentration up to 15% and CH₄/CO₂ ratio =1.

Язык оригинала	английский
Страницы (с-по)	363-376
Число страниц	14
Журнал	Open Chemistry
Том	14
Номер выпуска	1
DOI	https://doi.org/10.1515/chem-2016-0039
Состояние	Опубликовано - 1 янв 2016

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10.1515/chem-2016-0039

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Sadykov, V. A., Simonov, M. N., Mezentseva, N. V., Pavlova, S. N., Fedorova, Y. E., Bobin, A. S., Bespalko, Y. N., Ishchenko, A. V., Krieger, T. A., Glazneva, T. S., Larina, T. V., Cherepanova, S. V., Kaichev, V. V., Saraev, A. A., Chesalov, Y. A., Shmakov, A. N., Roger, A. C., & Adamski, A. (2016). Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH₄ dry reforming. Open Chemistry, 14(1), 363-376. https://doi.org/10.1515/chem-2016-0039

Sadykov, Vladislav A. ; Simonov, Mikhail N. ; Mezentseva, Natalia V. ; Pavlova, Svetlana N. ; Fedorova, Yulia E. ; Bobin, Aleksei S. ; Bespalko, Yulia N. ; Ishchenko, Arcady V. ; Krieger, Tamara A. ; Glazneva, Tatiana S. ; Larina, Tatyana V. ; Cherepanova, Svetlana V. ; Kaichev, Vasilii V. ; Saraev, Andrey A. ; Chesalov, Yurii A. ; Shmakov, Aleksandr N. ; Roger, Anne Cecile ; Adamski, Andrzej. / Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH₄ dry reforming. В: Open Chemistry. 2016 ; Том 14, № 1. стр. 363-376.

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title = "Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming",

abstract = "Mixed nanocrystalline Ce-Zr-O oxides (Ce/Zr = 1 or 7/3) were prepared by modified Pechini route using ethylene glycol solutions of metal salts. Detailed characterization of their real structure and surface properties by X-ray diffraction on synchrotron radiation with the full-profile Rietveld analysis, high resolution electron microscopy with elemental analysis, Raman spectroscopy, UV-Vis and X-ray photoelectron spectroscopy revealed a high homogeneity of cations distribution in nanodomains resulting in stabilization of disordered cubic phase. This provides a high dispersion of NiO loaded on these mixed oxides by wet impregnation, a high reactivity and mobility of oxygen in these catalysts and strong interaction of Ni with support in the reduced state. This helps to achieve a high activity and coking stability of developed catalysts in CH4 dry reforming in feeds with CH4 concentration up to 15% and CH4/CO2 ratio =1.",

keywords = "Ce-Zr-O oxide, coking stability, methane dry reforming, Ni stabilization",

author = "Sadykov, {Vladislav A.} and Simonov, {Mikhail N.} and Mezentseva, {Natalia V.} and Pavlova, {Svetlana N.} and Fedorova, {Yulia E.} and Bobin, {Aleksei S.} and Bespalko, {Yulia N.} and Ishchenko, {Arcady V.} and Krieger, {Tamara A.} and Glazneva, {Tatiana S.} and Larina, {Tatyana V.} and Cherepanova, {Svetlana V.} and Kaichev, {Vasilii V.} and Saraev, {Andrey A.} and Chesalov, {Yurii A.} and Shmakov, {Aleksandr N.} and Roger, {Anne Cecile} and Andrzej Adamski",

year = "2016",

month = jan,

day = "1",

doi = "10.1515/chem-2016-0039",

language = "English",

volume = "14",

pages = "363--376",

journal = "Open Chemistry",

issn = "2391-5420",

publisher = "Walter de Gruyter GmbH",

number = "1",

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Sadykov, VA , Simonov, MN, Mezentseva, NV, Pavlova, SN, Fedorova, YE, Bobin, AS, Bespalko, YN, Ishchenko, AV, Krieger, TA, Glazneva, TS, Larina, TV, Cherepanova, SV , Kaichev, VV , Saraev, AA, Chesalov, YA, Shmakov, AN, Roger, AC & Adamski, A 2016, 'Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH₄ dry reforming', Open Chemistry, том. 14, № 1, стр. 363-376. https://doi.org/10.1515/chem-2016-0039

Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH₄ dry reforming. / Sadykov, Vladislav A.; Simonov, Mikhail N.; Mezentseva, Natalia V.; Pavlova, Svetlana N.; Fedorova, Yulia E.; Bobin, Aleksei S.; Bespalko, Yulia N.; Ishchenko, Arcady V.; Krieger, Tamara A.; Glazneva, Tatiana S.; Larina, Tatyana V.; Cherepanova, Svetlana V.; Kaichev, Vasilii V.; Saraev, Andrey A.; Chesalov, Yurii A.; Shmakov, Aleksandr N.; Roger, Anne Cecile; Adamski, Andrzej.

В: Open Chemistry, Том 14, № 1, 01.01.2016, стр. 363-376.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Ni-loaded nanocrystalline ceria-zirconia solid solutions prepared via modified Pechini route as stable to coking catalysts of CH4 dry reforming

AU - Sadykov, Vladislav A.

AU - Simonov, Mikhail N.

AU - Mezentseva, Natalia V.

AU - Pavlova, Svetlana N.

AU - Fedorova, Yulia E.

AU - Bobin, Aleksei S.

AU - Bespalko, Yulia N.

AU - Ishchenko, Arcady V.

AU - Krieger, Tamara A.

AU - Glazneva, Tatiana S.

AU - Larina, Tatyana V.

AU - Cherepanova, Svetlana V.

AU - Kaichev, Vasilii V.

AU - Saraev, Andrey A.

AU - Chesalov, Yurii A.

AU - Shmakov, Aleksandr N.

AU - Roger, Anne Cecile

AU - Adamski, Andrzej

PY - 2016/1/1

Y1 - 2016/1/1

N2 - Mixed nanocrystalline Ce-Zr-O oxides (Ce/Zr = 1 or 7/3) were prepared by modified Pechini route using ethylene glycol solutions of metal salts. Detailed characterization of their real structure and surface properties by X-ray diffraction on synchrotron radiation with the full-profile Rietveld analysis, high resolution electron microscopy with elemental analysis, Raman spectroscopy, UV-Vis and X-ray photoelectron spectroscopy revealed a high homogeneity of cations distribution in nanodomains resulting in stabilization of disordered cubic phase. This provides a high dispersion of NiO loaded on these mixed oxides by wet impregnation, a high reactivity and mobility of oxygen in these catalysts and strong interaction of Ni with support in the reduced state. This helps to achieve a high activity and coking stability of developed catalysts in CH4 dry reforming in feeds with CH4 concentration up to 15% and CH4/CO2 ratio =1.

AB - Mixed nanocrystalline Ce-Zr-O oxides (Ce/Zr = 1 or 7/3) were prepared by modified Pechini route using ethylene glycol solutions of metal salts. Detailed characterization of their real structure and surface properties by X-ray diffraction on synchrotron radiation with the full-profile Rietveld analysis, high resolution electron microscopy with elemental analysis, Raman spectroscopy, UV-Vis and X-ray photoelectron spectroscopy revealed a high homogeneity of cations distribution in nanodomains resulting in stabilization of disordered cubic phase. This provides a high dispersion of NiO loaded on these mixed oxides by wet impregnation, a high reactivity and mobility of oxygen in these catalysts and strong interaction of Ni with support in the reduced state. This helps to achieve a high activity and coking stability of developed catalysts in CH4 dry reforming in feeds with CH4 concentration up to 15% and CH4/CO2 ratio =1.

KW - Ce-Zr-O oxide

KW - coking stability

KW - methane dry reforming

KW - Ni stabilization

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U2 - 10.1515/chem-2016-0039

DO - 10.1515/chem-2016-0039

M3 - Article

AN - SCOPUS:85013192693

VL - 14

SP - 363

EP - 376

JO - Open Chemistry

JF - Open Chemistry

SN - 2391-5420

IS - 1

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