Аннотация
The reaction of Ta(NMe2)5 with NHC·HBF4 (NHC = IMes and SIMes) leads to new carbene adducts of the mixed TaV amidofluoride, [(NHC)TaF3(NMe2)2]. On the contrary, the reaction of Ta(NMe2)5 with IMes·HCl gives a complex mixture, where [(aIMes)TaCl2(NMe2)3] is identified as one of the products. This is the first example of abnormal NHC coordination to an early transition metal.
Язык оригинала | английский |
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Страницы (с-по) | 4902-4906 |
Число страниц | 5 |
Журнал | Dalton Transactions |
Том | 46 |
Номер выпуска | 15 |
DOI | |
Состояние | Опубликовано - 21 апр 2017 |