New Sulfide Photocatalysts Modified by NiS and Ni(OH)(2) for Photocatalytic Hydrogen Production

D. V. Markovskaya; E. Yu. Gerasimov; E. A. Kozlova; V. N. Parmon

doi:10.1016/j.matpr.2017.09.003

New Sulfide Photocatalysts Modified by NiS and Ni(OH)(2) for Photocatalytic Hydrogen Production

D. V. Markovskaya, E. Yu. Gerasimov, E. A. Kozlova, V. N. Parmon

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

6 Цитирования (Scopus)

Аннотация

The photocatalytic properties of Cd_0.3Zn_0.7S modified by nickel sulfide and nickel hydroxide were studied. The obtained samples were characterized by a wide range of experimental techniques including X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy (DRS), and high resolution transmission electron microscopy (HRTEM). The photocatalytic activity was measured in the hydrogen evolution from aqueous solutions of Na₂S/Na₂SO₃ under visible light irradiation (λ = 450 nm). The highest photocatalytic activity and apparent quantum efficiency (AQE) were 6.12 mmol h^-1 g^-1 and 22.1%, respectively. A mechanism of the photoinduced transformations of the photocatalysts containing Ni(OH)₂, NiS, and Ni₃S₂ during hydrogen production was proposed.

Язык оригинала	английский
Страницы (с-по)	11331-11335
Число страниц	5
Журнал	Materials Today: Proceedings
Том	4
Номер выпуска	11
DOI	https://doi.org/10.1016/j.matpr.2017.09.003
Состояние	Опубликовано - 1 янв. 2017
Событие	Russia-Japan Conference on Advanced Materials - Synthesis, Processing and Properties of Nanostructures (RJCAM) - Novosibirsk Продолжительность: 31 окт. 2016 → 3 нояб. 2016

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10.1016/j.matpr.2017.09.003

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title = "New Sulfide Photocatalysts Modified by NiS and Ni(OH)(2) for Photocatalytic Hydrogen Production",

abstract = "The photocatalytic properties of Cd0.3Zn0.7S modified by nickel sulfide and nickel hydroxide were studied. The obtained samples were characterized by a wide range of experimental techniques including X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy (DRS), and high resolution transmission electron microscopy (HRTEM). The photocatalytic activity was measured in the hydrogen evolution from aqueous solutions of Na2S/Na2SO3 under visible light irradiation (λ = 450 nm). The highest photocatalytic activity and apparent quantum efficiency (AQE) were 6.12 mmol h-1 g-1 and 22.1%, respectively. A mechanism of the photoinduced transformations of the photocatalysts containing Ni(OH)2, NiS, and Ni3S2 during hydrogen production was proposed.",

keywords = "Photocatalytic hydrogen production, visible light, Cd0.3Zn0.7S, nickel-based co-catalyst, VISIBLE-LIGHT IRRADIATION, WATER, EVOLUTION, NI3S2",

author = "Markovskaya, {D. V.} and Gerasimov, {E. Yu.} and Kozlova, {E. A.} and Parmon, {V. N.}",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd.; Russia-Japan Conference on Advanced Materials - Synthesis, Processing and Properties of Nanostructures (RJCAM) ; Conference date: 31-10-2016 Through 03-11-2016",

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New Sulfide Photocatalysts Modified by NiS and Ni(OH)(2) for Photocatalytic Hydrogen Production. / Markovskaya, D. V.; Gerasimov, E. Yu.; Kozlova, E. A. и др.

В: Materials Today: Proceedings, Том 4, № 11, 01.01.2017, стр. 11331-11335.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - New Sulfide Photocatalysts Modified by NiS and Ni(OH)(2) for Photocatalytic Hydrogen Production

AU - Markovskaya, D. V.

AU - Gerasimov, E. Yu.

AU - Kozlova, E. A.

AU - Parmon, V. N.

PY - 2017/1/1

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KW - Cd0.3Zn0.7S

KW - nickel-based co-catalyst

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