New scandium borates RxLayScz(BO3)4 (x+y+z=4, R=Sm, Tb): Synthesis, growth, structure and optical properties

A. Kuznetsov; A. Kokh; N. Kononova; V. Shevchenko; B. Uralbekov; D. Ezhov; V. Svetlichnyi; A. Goreiavcheva; K. Kokh

doi:10.1016/j.materresbull.2020.110850

New scandium borates R_xLa_ySc_z(BO₃)₄ (x+y+z=4, R=Sm, Tb): Synthesis, growth, structure and optical properties

A. Kuznetsov, A. Kokh, N. Kononova, V. Shevchenko, B. Uralbekov, D. Ezhov, V. Svetlichnyi, A. Goreiavcheva, K. Kokh

Кафедра минералогии и геохимии ГГФ

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

2 Цитирования (Scopus)

Аннотация

Herein we report the growth of new R_xLa_ySc_z(BO₃)₄ (x + y+z = 4, R = Sm, Tb) crystals with large second-harmonic generation (SHG) responses. The obtained compounds, grown from eutectic LiBO₂-LiF flux by the TSSG method, crystallize in the space group P321 with the cell parameters a = 9.800(15) Å and c = 7.9565(7) Å for Sm_0.34La_0.68Sc_2.98(BO₃)₄ and a = 9.7976(7) Å and c = 7.9567(12) Å for Tb_0.23La_0.77Sc₃(BO₃)₄. These crystalline materials also exhibit luminescent properties related to the optical transitions of Tb³⁺ and Sm³⁺; specifically, Tb_0.23La_0.77Sc₃(BO₃)₄ shows a strong green emission that is dominated by the ⁵D₄ to ⁷F₅ transition. The studied crystals’ SHG intensities were higher than those of KDP crystals, revealing their potential uses in various nonlinear optics applications.

Язык оригинала	английский
Номер статьи	110850
Число страниц	6
Журнал	Materials Research Bulletin
Том	126
DOI	https://doi.org/10.1016/j.materresbull.2020.110850
Состояние	Опубликовано - июн. 2020

Предметные области OECD FOS+WOS

2.05 ТЕХНОЛОГИЯ МАТЕРИАЛОВ

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10.1016/j.materresbull.2020.110850

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title = "New scandium borates RxLayScz(BO3)4 (x+y+z=4, R=Sm, Tb): Synthesis, growth, structure and optical properties",

abstract = "Herein we report the growth of new RxLayScz(BO3)4 (x + y+z = 4, R = Sm, Tb) crystals with large second-harmonic generation (SHG) responses. The obtained compounds, grown from eutectic LiBO2-LiF flux by the TSSG method, crystallize in the space group P321 with the cell parameters a = 9.800(15) {\AA} and c = 7.9565(7) {\AA} for Sm0.34La0.68Sc2.98(BO3)4 and a = 9.7976(7) {\AA} and c = 7.9567(12) {\AA} for Tb0.23La0.77Sc3(BO3)4. These crystalline materials also exhibit luminescent properties related to the optical transitions of Tb3+ and Sm3+; specifically, Tb0.23La0.77Sc3(BO3)4 shows a strong green emission that is dominated by the 5D4 to 7F5 transition. The studied crystals{\textquoteright} SHG intensities were higher than those of KDP crystals, revealing their potential uses in various nonlinear optics applications.",

keywords = "Crystal growth, Huntite, Luminiscent, Rare earth borate, SHG, CRYSTAL-STRUCTURE, ND, GROWTH",

author = "A. Kuznetsov and A. Kokh and N. Kononova and V. Shevchenko and B. Uralbekov and D. Ezhov and V. Svetlichnyi and A. Goreiavcheva and K. Kokh",

year = "2020",

month = jun,

doi = "10.1016/j.materresbull.2020.110850",

language = "English",

volume = "126",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier Ltd",

}

New scandium borates R_xLa_ySc_z(BO₃)₄ (x+y+z=4, R=Sm, Tb): Synthesis, growth, structure and optical properties. / Kuznetsov, A.; Kokh, A.; Kononova, N. и др.

В: Materials Research Bulletin, Том 126, 110850, 06.2020.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - New scandium borates RxLayScz(BO3)4 (x+y+z=4, R=Sm, Tb): Synthesis, growth, structure and optical properties

AU - Kuznetsov, A.

AU - Kokh, A.

AU - Kononova, N.

AU - Shevchenko, V.

AU - Uralbekov, B.

AU - Ezhov, D.

AU - Svetlichnyi, V.

AU - Goreiavcheva, A.

AU - Kokh, K.

PY - 2020/6

Y1 - 2020/6

N2 - Herein we report the growth of new RxLayScz(BO3)4 (x + y+z = 4, R = Sm, Tb) crystals with large second-harmonic generation (SHG) responses. The obtained compounds, grown from eutectic LiBO2-LiF flux by the TSSG method, crystallize in the space group P321 with the cell parameters a = 9.800(15) Å and c = 7.9565(7) Å for Sm0.34La0.68Sc2.98(BO3)4 and a = 9.7976(7) Å and c = 7.9567(12) Å for Tb0.23La0.77Sc3(BO3)4. These crystalline materials also exhibit luminescent properties related to the optical transitions of Tb3+ and Sm3+; specifically, Tb0.23La0.77Sc3(BO3)4 shows a strong green emission that is dominated by the 5D4 to 7F5 transition. The studied crystals’ SHG intensities were higher than those of KDP crystals, revealing their potential uses in various nonlinear optics applications.

AB - Herein we report the growth of new RxLayScz(BO3)4 (x + y+z = 4, R = Sm, Tb) crystals with large second-harmonic generation (SHG) responses. The obtained compounds, grown from eutectic LiBO2-LiF flux by the TSSG method, crystallize in the space group P321 with the cell parameters a = 9.800(15) Å and c = 7.9565(7) Å for Sm0.34La0.68Sc2.98(BO3)4 and a = 9.7976(7) Å and c = 7.9567(12) Å for Tb0.23La0.77Sc3(BO3)4. These crystalline materials also exhibit luminescent properties related to the optical transitions of Tb3+ and Sm3+; specifically, Tb0.23La0.77Sc3(BO3)4 shows a strong green emission that is dominated by the 5D4 to 7F5 transition. The studied crystals’ SHG intensities were higher than those of KDP crystals, revealing their potential uses in various nonlinear optics applications.

KW - Crystal growth

KW - Huntite

KW - Luminiscent

KW - Rare earth borate

KW - SHG

KW - CRYSTAL-STRUCTURE

KW - ND

KW - GROWTH

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U2 - 10.1016/j.materresbull.2020.110850

DO - 10.1016/j.materresbull.2020.110850

M3 - Article

AN - SCOPUS:85081035900

VL - 126

JO - Materials Research Bulletin

JF - Materials Research Bulletin

SN - 0025-5408

M1 - 110850

ER -