New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re                         
                        6
                                                 (μ                         
                        3
                                                 -Q)                         
                        8
                                                 }(CN)                         
                        6
                                                 ]                         
                        4–
                                                  (Q = S, Se, Te)

A. S. Pronin; S. S. Yarovoy; A. I. Smolentsev; Yu V. Mironov

doi:10.1134/S1070328419020052

New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re ₆ (μ ₃ -Q) ₈ }(CN) ₆ ] ^4– (Q = S, Se, Te)

A. S. Pronin, S. S. Yarovoy, A. I. Smolentsev, Yu V. Mironov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

A new method is proposed for the synthesis of the octahedral rhenium chalcocyanide cluster complexes [{Re ₆ (μ ₃ -Q) ₈ }(CN) ₆ ] ^4– (Q = S, Se, Te) using rhenium(IV) oxide as the starting compound. Among the synthesized compounds, the anhydrous cluster salt K ₄ [{Re ₆ Se ₈ }(CN) ₆ ] is characterized by X-ray diffraction analysis for the first time. The crystals are orthorhombic, space group Pbcn; a = 13.1386(13), b = 11.4941(8), c = 17.2990(16) Å, Z = 4, V = 2612.4(4) Å ³ (CIF file IСSD no. 434320). The crystal structure of K ₄ [{Re ₆ Se ₈ }(CN) ₆ ] represents a framework type packing based on the K ⁺ cations coordinated by the cyanide groups of the cluster anions [{Re ₆ Se ₈ }(CN) ₆ ] ^4– .

Язык оригинала	английский
Страницы (с-по)	119-123
Число страниц	5
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	45
Номер выпуска	2
DOI	https://doi.org/10.1134/S1070328419020052
Состояние	Опубликовано - 1 фев 2019

Доступ к документу

10.1134/S1070328419020052

Link to publication in Scopus

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Цитировать

Pronin, A. S., Yarovoy, S. S., Smolentsev, A. I., & Mironov, Y. V. (2019). New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re ₆ (μ ₃ -Q) ₈ }(CN) ₆ ] ^4– (Q = S, Se, Te). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 45(2), 119-123. https://doi.org/10.1134/S1070328419020052

Pronin, A. S. ; Yarovoy, S. S. ; Smolentsev, A. I. ; Mironov, Yu V. / New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re ₆ (μ ₃ -Q) ₈ }(CN) ₆ ] ^4– (Q = S, Se, Te). В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 ; Том 45, № 2. стр. 119-123.

@article{737d6464d4044ca9b88b122ec9d6c5a7,

title = "New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te)",

abstract = "A new method is proposed for the synthesis of the octahedral rhenium chalcocyanide cluster complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te) using rhenium(IV) oxide as the starting compound. Among the synthesized compounds, the anhydrous cluster salt K 4 [{Re 6 Se 8 }(CN) 6 ] is characterized by X-ray diffraction analysis for the first time. The crystals are orthorhombic, space group Pbcn; a = 13.1386(13), b = 11.4941(8), c = 17.2990(16) {\AA}, Z = 4, V = 2612.4(4) {\AA} 3 (CIF file IСSD no. 434320). The crystal structure of K 4 [{Re 6 Se 8 }(CN) 6 ] represents a framework type packing based on the K + cations coordinated by the cyanide groups of the cluster anions [{Re 6 Se 8 }(CN) 6 ] 4– . ",

keywords = "chalcogens, crystal structure, octahedral cluster complex, rhenium",

author = "Pronin, {A. S.} and Yarovoy, {S. S.} and Smolentsev, {A. I.} and Mironov, {Yu V.}",

year = "2019",

month = feb,

day = "1",

doi = "10.1134/S1070328419020052",

language = "English",

volume = "45",

pages = "119--123",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

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Pronin, AS, Yarovoy, SS, Smolentsev, AI & Mironov, YV 2019, 'New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re ₆ (μ ₃ -Q) ₈ }(CN) ₆ ] ^4– (Q = S, Se, Te)', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, том. 45, № 2, стр. 119-123. https://doi.org/10.1134/S1070328419020052

New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re ₆ (μ ₃ -Q) ₈ }(CN) ₆ ] ^4– (Q = S, Se, Te). / Pronin, A. S.; Yarovoy, S. S.; Smolentsev, A. I.; Mironov, Yu V.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 45, № 2, 01.02.2019, стр. 119-123.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te)

AU - Pronin, A. S.

AU - Yarovoy, S. S.

AU - Smolentsev, A. I.

AU - Mironov, Yu V.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - A new method is proposed for the synthesis of the octahedral rhenium chalcocyanide cluster complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te) using rhenium(IV) oxide as the starting compound. Among the synthesized compounds, the anhydrous cluster salt K 4 [{Re 6 Se 8 }(CN) 6 ] is characterized by X-ray diffraction analysis for the first time. The crystals are orthorhombic, space group Pbcn; a = 13.1386(13), b = 11.4941(8), c = 17.2990(16) Å, Z = 4, V = 2612.4(4) Å 3 (CIF file IСSD no. 434320). The crystal structure of K 4 [{Re 6 Se 8 }(CN) 6 ] represents a framework type packing based on the K + cations coordinated by the cyanide groups of the cluster anions [{Re 6 Se 8 }(CN) 6 ] 4– .

AB - A new method is proposed for the synthesis of the octahedral rhenium chalcocyanide cluster complexes [{Re 6 (μ 3 -Q) 8 }(CN) 6 ] 4– (Q = S, Se, Te) using rhenium(IV) oxide as the starting compound. Among the synthesized compounds, the anhydrous cluster salt K 4 [{Re 6 Se 8 }(CN) 6 ] is characterized by X-ray diffraction analysis for the first time. The crystals are orthorhombic, space group Pbcn; a = 13.1386(13), b = 11.4941(8), c = 17.2990(16) Å, Z = 4, V = 2612.4(4) Å 3 (CIF file IСSD no. 434320). The crystal structure of K 4 [{Re 6 Se 8 }(CN) 6 ] represents a framework type packing based on the K + cations coordinated by the cyanide groups of the cluster anions [{Re 6 Se 8 }(CN) 6 ] 4– .

KW - chalcogens

KW - crystal structure

KW - octahedral cluster complex

KW - rhenium

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U2 - 10.1134/S1070328419020052

DO - 10.1134/S1070328419020052

M3 - Article

AN - SCOPUS:85064811771

VL - 45

SP - 119

EP - 123

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 2

ER -

Pronin AS, Yarovoy SS, Smolentsev AI, Mironov YV. New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re ₆ (μ ₃ -Q) ₈ }(CN) ₆ ] ^4– (Q = S, Se, Te). Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 Февр. 1;45(2):119-123. https://doi.org/10.1134/S1070328419020052