New heteroleptic iridium(III) nitro complexes derived from fac-[Ir(NO2)3(H2O)3]

Polina Topchiyan, Danila Vasilchenko, Sergey Tkachev, Iraida Baidina, Ilya Korolkov, Dmitriy Sheven, Semen Berdyugin, Sergey Korenev

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

An aqueous solution of fac-[Ir(H2O)3(NO2)3] (1) was utilized as a starting material for preparation of the new heteroleptic iridium complex [Ir(H2O) (bpy) (NO2)3] (2). From alkaline solutions of 2, the salt Na [Ir(OH) (NO2)3 (bpy)]·2H2O was isolated and its structure was determined by X-ray structure analysis. Structures of new compounds 2 and 3 as well as the parent complex 1 was characterized using multinuclear magnetic resonance spectroscopy and mass spectrometry. The structures of parent fac-[Ir(H2O)3(NO2)3] and complexes 2 and 3 were probed by employing density functional theory (DFT) calculations.

Язык оригиналаанглийский
Страницы (с-по)100-108
Число страниц9
ЖурналJournal of Molecular Structure
Том1182
DOI
СостояниеОпубликовано - 15 апр 2019

Fingerprint Подробные сведения о темах исследования «New heteroleptic iridium(III) nitro complexes derived from fac-[Ir(NO<sub>2</sub>)<sub>3</sub>(H<sub>2</sub>O)<sub>3</sub>]». Вместе они формируют уникальный семантический отпечаток (fingerprint).

  • Цитировать