Аннотация

The crystal structure of the double complex salt (DCS) [PdEn2]3[Rh(NO2)6]2 • 2.67H2O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group P1 ¯ , Z = 4, a = 9.2331(3) Å, b = 9.9136(4) Å, c = 13.7824(5) Å, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) Å3, ρcalcd = 2.141 g/cm3, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd0.45Rh0.55 and Pd0.95Rh0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd0.6Rh0.4 solid solution.

Язык оригиналаанглийский
Страницы (с-по)886-892
Число страниц7
ЖурналRussian Journal of Inorganic Chemistry
Том62
Номер выпуска7
DOI
СостояниеОпубликовано - 1 июл 2017

Fingerprint Подробные сведения о темах исследования «New double complex salt [PdEn<sub>2</sub>]<sub>3</sub>[Rh(NO<sub>2</sub>)<sub>6</sub>]<sub>2</sub> · 2.67H<sub>2</sub>O: Synthesis, crystal structure, and thermal properties». Вместе они формируют уникальный семантический отпечаток (fingerprint).

  • Цитировать