New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O: Synthesis, crystal structure, and thermal properties

A. K. Kirilovich; P. E. Plyusnin; D. A. Piryazev; S. A. Gromilov; S. V. Korenev

doi:10.1134/S0036023617070099

New double complex salt [PdEn₂]₃[Rh(NO₂)₆]₂ · 2.67H₂O: Synthesis, crystal structure, and thermal properties

A. K. Kirilovich, P. E. Plyusnin, D. A. Piryazev, S. A. Gromilov, S. V. Korenev

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

The crystal structure of the double complex salt (DCS) [PdEn₂]₃[Rh(NO₂)₆]₂ • 2.67H₂O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group P1 ¯ , Z = 4, a = 9.2331(3) Å, b = 9.9136(4) Å, c = 13.7824(5) Å, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) Å³, ρ_calcd = 2.141 g/cm³, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd_0.45Rh_0.55 and Pd_0.95Rh_0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd_0.6Rh_0.4 solid solution.

Язык оригинала	английский
Страницы (с-по)	886-892
Число страниц	7
Журнал	Russian Journal of Inorganic Chemistry
Том	62
Номер выпуска	7
DOI	https://doi.org/10.1134/S0036023617070099
Состояние	Опубликовано - 1 июл 2017

Доступ к документу

10.1134/S0036023617070099

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Цитировать

Kirilovich, A. K., Plyusnin, P. E., Piryazev, D. A., Gromilov, S. A., & Korenev, S. V. (2017). New double complex salt [PdEn₂]₃[Rh(NO₂)₆]₂ · 2.67H₂O: Synthesis, crystal structure, and thermal properties. Russian Journal of Inorganic Chemistry, 62(7), 886-892. https://doi.org/10.1134/S0036023617070099

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abstract = "The crystal structure of the double complex salt (DCS) [PdEn2]3[Rh(NO2)6]2 • 2.67H2O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group P1 ¯ , Z = 4, a = 9.2331(3) {\AA}, b = 9.9136(4) {\AA}, c = 13.7824(5) {\AA}, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) {\AA}3, ρcalcd = 2.141 g/cm3, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd0.45Rh0.55 and Pd0.95Rh0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd0.6Rh0.4 solid solution.",

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New double complex salt [PdEn₂]₃[Rh(NO₂)₆]₂ · 2.67H₂O : Synthesis, crystal structure, and thermal properties. / Kirilovich, A. K.; Plyusnin, P. E.; Piryazev, D. A.; Gromilov, S. A.; Korenev, S. V.

В: Russian Journal of Inorganic Chemistry, Том 62, № 7, 01.07.2017, стр. 886-892.

Результат исследования: Научные публикации в периодических изданиях › статья

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T2 - Synthesis, crystal structure, and thermal properties

AU - Kirilovich, A. K.

AU - Plyusnin, P. E.

AU - Piryazev, D. A.

AU - Gromilov, S. A.

AU - Korenev, S. V.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - The crystal structure of the double complex salt (DCS) [PdEn2]3[Rh(NO2)6]2 • 2.67H2O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group P1 ¯ , Z = 4, a = 9.2331(3) Å, b = 9.9136(4) Å, c = 13.7824(5) Å, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) Å3, ρcalcd = 2.141 g/cm3, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd0.45Rh0.55 and Pd0.95Rh0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd0.6Rh0.4 solid solution.

AB - The crystal structure of the double complex salt (DCS) [PdEn2]3[Rh(NO2)6]2 • 2.67H2O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group P1 ¯ , Z = 4, a = 9.2331(3) Å, b = 9.9136(4) Å, c = 13.7824(5) Å, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) Å3, ρcalcd = 2.141 g/cm3, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd0.45Rh0.55 and Pd0.95Rh0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd0.6Rh0.4 solid solution.

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