Neutral Chalcogenide Tungsten Cluster with Tris(2-Cyanoethyl)phosphine

Alena D. Gassan, Anton A. Ivanov, Ilia V. Eltsov, Natalia V. Kuratieva, Michael A. Shestopalov

Результат исследования: Научные публикации в периодических изданияхстатьярецензирование


Despite the great prospects for the use of octahedral metal cluster complexes in various fields, chalcogenide tungsten compounds with functional organic ligands have practically not been studied. In this work, we present the synthesis and detailed characterization of a tungsten cluster with tris(2-cyanoethyl)phosphine [{W6S8}(P(C2H4CN)3)6]. The compound has been obtained directly from (Bu4N)2[{W6Cl8}Cl6] in one step with a good yield. The crystal structure, determined by single-crystal X-ray diffraction analysis, as well as multinuclear NMR analysis have well confirmed the formation of the chalcogenide neutral cluster. Moreover, the electrochemical properties of the complex have been studied.

Язык оригиналаанглийский
Страницы (с-по)2896-2899
Число страниц4
ЖурналEuropean Journal of Inorganic Chemistry
Номер выпуска30
СостояниеОпубликовано - 16 авг 2020

Предметные области OECD FOS+WOS



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