Network Coordination Polymers Based on Thieno[3,2-b]Thiophene-2,5-Dicarboxylic Acid

A. M. Samsonova; V. A. Bolotov; D. G. Samsonenko; D. N. Dybtsev; V. P. Fedin

doi:10.1134/S0022476619090117

Network Coordination Polymers Based on Thieno[3,2-b]Thiophene-2,5-Dicarboxylic Acid

A. M. Samsonova, V. A. Bolotov, D. G. Samsonenko, D. N. Dybtsev, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

Heating the solutions of Mn(II), Cd(II) salts and thieno[3,2-b]thiophene-2,5-dicarboxylic acid (H₂[3,2-b]ttdc) in N,N-dimethylformamide (DMF) or N,N-dimethylacetamide (DMA) results in the formation of crystalline complex compounds [Mn₂([3,2-b]ttdc)₂(dmf)₂]·4DMF (1), [Cd₂([3,2-b]ttdc)₂(dmf)₂]·2DMF (2), and [Mn₂([3,2-b]ttdc)₂(dma)₂]·2[Mn(dma)₆](ClO₄)₂ (3). According to the X-ray diffraction data, the compounds are two-dimensional layered coordination polymers with square network topologies. In compounds 1 and 2 the layers are shifted relative to each other, while in 3 the layers are located exactly one above another to form extended 9.5×13.0 Å channels occupied by solvated [Mn(dma)₆]²⁺ complex cations and perchlorate ClO₄ ⁻ anions located mainly near thienothiophene groups.

Язык оригинала	английский
Страницы (с-по)	1468-1473
Число страниц	6
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	9
DOI	https://doi.org/10.1134/S0022476619090117
Состояние	Опубликовано - 1 сент. 2019

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1.04 ХИМИЧЕСКИЕ НАУКИ

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@article{a70319eec42348d2808111772800b26f,

title = "Network Coordination Polymers Based on Thieno[3,2-b]Thiophene-2,5-Dicarboxylic Acid",

abstract = "Heating the solutions of Mn(II), Cd(II) salts and thieno[3,2-b]thiophene-2,5-dicarboxylic acid (H2[3,2-b]ttdc) in N,N-dimethylformamide (DMF) or N,N-dimethylacetamide (DMA) results in the formation of crystalline complex compounds [Mn2([3,2-b]ttdc)2(dmf)2]·4DMF (1), [Cd2([3,2-b]ttdc)2(dmf)2]·2DMF (2), and [Mn2([3,2-b]ttdc)2(dma)2]·2[Mn(dma)6](ClO4)2 (3). According to the X-ray diffraction data, the compounds are two-dimensional layered coordination polymers with square network topologies. In compounds 1 and 2 the layers are shifted relative to each other, while in 3 the layers are located exactly one above another to form extended 9.5×13.0 {\AA} channels occupied by solvated [Mn(dma)6]2+ complex cations and perchlorate ClO4 − anions located mainly near thienothiophene groups.",

keywords = "cadmium complexes, crystal structure, ligand, manganese complexes, metal-organic coordination polymer, thienothiophenedicarboxylate, METAL-ORGANIC FRAMEWORKS",

author = "Samsonova, {A. M.} and Bolotov, {V. A.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

note = "Funding Information: The study was supported by the Russian Science Foundation (project No. 8-13-00203). Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Inc. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",

year = "2019",

month = sep,

day = "1",

doi = "10.1134/S0022476619090117",

language = "English",

volume = "60",

pages = "1468--1473",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "9",

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Network Coordination Polymers Based on Thieno[3,2-b]Thiophene-2,5-Dicarboxylic Acid. / Samsonova, A. M.; Bolotov, V. A.; Samsonenko, D. G. и др.

В: Journal of Structural Chemistry, Том 60, № 9, 01.09.2019, стр. 1468-1473.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Network Coordination Polymers Based on Thieno[3,2-b]Thiophene-2,5-Dicarboxylic Acid

AU - Samsonova, A. M.

AU - Bolotov, V. A.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

N1 - Funding Information: The study was supported by the Russian Science Foundation (project No. 8-13-00203). Publisher Copyright: © 2019, Pleiades Publishing, Inc. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - Heating the solutions of Mn(II), Cd(II) salts and thieno[3,2-b]thiophene-2,5-dicarboxylic acid (H2[3,2-b]ttdc) in N,N-dimethylformamide (DMF) or N,N-dimethylacetamide (DMA) results in the formation of crystalline complex compounds [Mn2([3,2-b]ttdc)2(dmf)2]·4DMF (1), [Cd2([3,2-b]ttdc)2(dmf)2]·2DMF (2), and [Mn2([3,2-b]ttdc)2(dma)2]·2[Mn(dma)6](ClO4)2 (3). According to the X-ray diffraction data, the compounds are two-dimensional layered coordination polymers with square network topologies. In compounds 1 and 2 the layers are shifted relative to each other, while in 3 the layers are located exactly one above another to form extended 9.5×13.0 Å channels occupied by solvated [Mn(dma)6]2+ complex cations and perchlorate ClO4 − anions located mainly near thienothiophene groups.

AB - Heating the solutions of Mn(II), Cd(II) salts and thieno[3,2-b]thiophene-2,5-dicarboxylic acid (H2[3,2-b]ttdc) in N,N-dimethylformamide (DMF) or N,N-dimethylacetamide (DMA) results in the formation of crystalline complex compounds [Mn2([3,2-b]ttdc)2(dmf)2]·4DMF (1), [Cd2([3,2-b]ttdc)2(dmf)2]·2DMF (2), and [Mn2([3,2-b]ttdc)2(dma)2]·2[Mn(dma)6](ClO4)2 (3). According to the X-ray diffraction data, the compounds are two-dimensional layered coordination polymers with square network topologies. In compounds 1 and 2 the layers are shifted relative to each other, while in 3 the layers are located exactly one above another to form extended 9.5×13.0 Å channels occupied by solvated [Mn(dma)6]2+ complex cations and perchlorate ClO4 − anions located mainly near thienothiophene groups.

KW - cadmium complexes

KW - crystal structure

KW - ligand

KW - manganese complexes

KW - metal-organic coordination polymer

KW - thienothiophenedicarboxylate

KW - METAL-ORGANIC FRAMEWORKS

UR - http://www.scopus.com/inward/record.url?scp=85073874798&partnerID=8YFLogxK

U2 - 10.1134/S0022476619090117

DO - 10.1134/S0022476619090117

M3 - Article

AN - SCOPUS:85073874798

VL - 60

SP - 1468

EP - 1473

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 9

ER -