Natural analogue approaches to prediction of long-term behaviour of Ca2UO5∙2-3H2O X-phase: case study from Tulul Al Hammam site, Jordan

E. V. Sokol, S. N. Kokh, H. N. Khoury, Yu V. Seryotkin, S. V. Goryainov, S. A. Novikova, I. A. Sokol

Результат исследования: Научные публикации в периодических изданияхстатьярецензирование

3 Цитирования (Scopus)


The Tulul Al Hammam area in central Jordan is an advantageous natural analogue site to study long-term U(VI) retention in ~ 1 Ma old U-bearing combustion metamorphic marbles with clinker-like mineralogy exposed to prolonged supergene alteration for at least ~ 100 kyr. The marbles contain abundant grains of high-temperature (ca. 800–850 °C) primary double Ca-U(VI) oxides (mainly Ca3UO6 and CaUO4), which are commonly replaced by hydrated calcium uranates with various impurities (Si, Fe, Al and F). A more hydrous natural analogue of X-phase (Ca2UO5·2-3H2O) occurs as a predominant secondary U compound after primary Ca-U(VI) oxides. The phase was studied by single-crystal XRD, SEM/EDX and electron microprobe (EPMA) analyses and Raman spectroscopy. It is a non-crystalline phase with a specific finger-like microtexture consisting of thin (no wider than 1–2 μm) lamellar particles. Its Raman spectrum shows a single strong band at 706–713 cm−1, sometimes coexisting with up to three weak diffuse bands (ν ~ 390, ~ 540 and 1355–1400 cm−1). The find of the natural X-phase (Ca2UO5·2-3H2O) is evidence of its long-term stability in a natural environment. It proves explicitly that the compound Ca2UO5·nH2O is a solubility-limiting phase in aged cements. The results have implications for geological disposal of radioactive wastes.

Язык оригиналаанглийский
Номер статьи512
Число страниц14
ЖурналArabian Journal of Geosciences
Номер выпуска23
СостояниеОпубликовано - 1 дек 2017


Подробные сведения о темах исследования «Natural analogue approaches to prediction of long-term behaviour of Ca<sub>2</sub>UO<sub>5</sub>∙2-3H<sub>2</sub>O X-phase: case study from Tulul Al Hammam site, Jordan». Вместе они формируют уникальный семантический отпечаток (fingerprint).