Mononuclear Molybdenum Oxohalide Complexes (Bu4N)[MoOCl4(H2O)] and (Bu4N)[MoOBr4(H2O)]: Synthesis and Crystal Structures

S. A. Adonin; L. I. Udalova; P. A. Abramov; M. N. Sokolov; V. P. Fedin

doi:10.1134/S1070328418110015

Mononuclear Molybdenum Oxohalide Complexes (Bu₄N)[MoOCl₄(H₂O)] and (Bu₄N)[MoOBr₄(H₂O)]: Synthesis and Crystal Structures

S. A. Adonin, L. I. Udalova, P. A. Abramov, M. N. Sokolov, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

Abstract: The oxidation of K₃[MoCl₆] with air oxygen in aqueous solutions of HX (X = Cl, Br) in the presence of n-tetrabutylammonium salts affords mononuclear heteroligand complexes (Bu₄N)[MoOCl₄(H₂O)] (I) and (Bu₄N)[MoOBr₄(H₂O)] (II). The complexes are characterized by X-ray diffraction analysis (СIF files CCDC nos. 1812657 (I) and 1812658 (II).

Язык оригинала	английский
Страницы (с-по)	673-677
Число страниц	5
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	44
Номер выпуска	11
DOI	https://doi.org/10.1134/S1070328418110015
Состояние	Опубликовано - 1 ноя 2018

Доступ к документу

10.1134/S1070328418110015

Link to publication in Scopus

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title = "Mononuclear Molybdenum Oxohalide Complexes (Bu4N)[MoOCl4(H2O)] and (Bu4N)[MoOBr4(H2O)]: Synthesis and Crystal Structures",

abstract = "Abstract: The oxidation of K3[MoCl6] with air oxygen in aqueous solutions of HX (X = Cl, Br) in the presence of n-tetrabutylammonium salts affords mononuclear heteroligand complexes (Bu4N)[MoOCl4(H2O)] (I) and (Bu4N)[MoOBr4(H2O)] (II). The complexes are characterized by X-ray diffraction analysis (СIF files CCDC nos. 1812657 (I) and 1812658 (II).",

keywords = "halide complexes, heteroligand complexes, molybdenum, X-ray diffraction analysis, HALIDES, CORE, LIGANDS, OXOTETRABROMOMOLYBDENUM(V), PYRIDINE",

author = "Adonin, {S. A.} and Udalova, {L. I.} and Abramov, {P. A.} and Sokolov, {M. N.} and Fedin, {V. P.}",

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Mononuclear Molybdenum Oxohalide Complexes (Bu₄N)[MoOCl₄(H₂O)] and (Bu₄N)[MoOBr₄(H₂O)] : Synthesis and Crystal Structures. / Adonin, S. A.; Udalova, L. I.; Abramov, P. A.; Sokolov, M. N.; Fedin, V. P.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 44, № 11, 01.11.2018, стр. 673-677.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Mononuclear Molybdenum Oxohalide Complexes (Bu4N)[MoOCl4(H2O)] and (Bu4N)[MoOBr4(H2O)]

T2 - Synthesis and Crystal Structures

AU - Adonin, S. A.

AU - Udalova, L. I.

AU - Abramov, P. A.

AU - Sokolov, M. N.

AU - Fedin, V. P.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - Abstract: The oxidation of K3[MoCl6] with air oxygen in aqueous solutions of HX (X = Cl, Br) in the presence of n-tetrabutylammonium salts affords mononuclear heteroligand complexes (Bu4N)[MoOCl4(H2O)] (I) and (Bu4N)[MoOBr4(H2O)] (II). The complexes are characterized by X-ray diffraction analysis (СIF files CCDC nos. 1812657 (I) and 1812658 (II).

AB - Abstract: The oxidation of K3[MoCl6] with air oxygen in aqueous solutions of HX (X = Cl, Br) in the presence of n-tetrabutylammonium salts affords mononuclear heteroligand complexes (Bu4N)[MoOCl4(H2O)] (I) and (Bu4N)[MoOBr4(H2O)] (II). The complexes are characterized by X-ray diffraction analysis (СIF files CCDC nos. 1812657 (I) and 1812658 (II).

KW - halide complexes

KW - heteroligand complexes

KW - molybdenum

KW - X-ray diffraction analysis

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KW - CORE

KW - LIGANDS

KW - OXOTETRABROMOMOLYBDENUM(V)

KW - PYRIDINE

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M3 - Article

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JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

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