Monolithic rod columns for HPLC based on divinylbenzene-styrene copolymer with 1-vinylimidazole and 4-vinylpyridine

Yuri Patrushev, Yulia Yudina, Vladimir Sidelnikov

Результат исследования: Научные публикации в периодических изданияхстатья

4 Цитирования (Scopus)

Аннотация

Monolithic chromatographic columns for HPLC based on divinylbenzene-styrene both with 1-vinylimidazole and with 4-vinylpyridine are prepared. The monoliths were synthesized in glass tubes with the inner diameter of 2 mm. Texture, hydrodynamic and chromatographic properties of the prepared columns were studied. Linear solvation energy relationships model was applied for the characterization of columns selectivity It is shown that changing the on 1-vinylimidazole or 4-vinylpyridine content in the initial solution allows to change the selectivity of the columns. An examples of small molecules and some proteins separations are presented.

Язык оригиналаанглийский
Страницы (с-по)458-466
Число страниц9
ЖурналJournal of Liquid Chromatography and Related Technologies
Том41
Номер выпуска8
DOI
СостояниеОпубликовано - 9 мая 2018

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